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101

Decomposition of some free radical initiators in hexamethyldisilane

Hideki Sakurai, Tamon Kishida, Akira Hosomi, Makoto Kumada

Journal:

Journal of Organometallic Chemistry

Year:

1967

Language:

english

File:

PDF, 315 KB

english, 1967

102

Thermal SiSi/SiSi redistribution of hexaorganodisilane. A new thermally 'forbidden' molecular reaction

Hideki Sakurai, Akira Hosomi

Journal:

Journal of Organometallic Chemistry

Year:

1972

Language:

english

File:

PDF, 154 KB

english, 1972

103

Organogermanium compounds : IV. Novel phenyl migrations from carbon to germanium and from germanium to carbon

Hideki Sakurai, Ikuo Nozue, Akira Hosomi

Journal:

Journal of Organometallic Chemistry

Year:

1974

Language:

english

File:

PDF, 489 KB

english, 1974

104

Acid-catalyzed intramolecular addition of a carboxy group to vinylsilanes

Katsukiyo Miura, Joji Hayashida, Tatsuyuki Takahashi, Hisashi Nishikori, Akira Hosomi

Journal:

Journal of Organometallic Chemistry

Year:

2003

Language:

english

File:

PDF, 284 KB

english, 2003

105

Highly stereoselective metathesis reaction between optically active hydrosilane and copper(I) salt in 1,3-dimethyl-2-imidazolidinone

Hajime Ito, Tomoko Ishizuka, Tomoko Okumura, Hiroshi Yamanaka, Jun-ichi Tateiwa, Motohiro Sonoda, Akira Hosomi

Journal:

Journal of Organometallic Chemistry

Year:

1999

Language:

english

File:

PDF, 86 KB

english, 1999

106

Chemistry of organosilicon compounds—165 : 2-Trimethylsilyl-methyl-1, 3-Butadiene—A versatile building block for terpene synthesis

Hideki sakurai, Akira Hosomi, Masaki Saito, Koshi Sasaki, Hirokazu Iguchi, Jun-Ichi Sasaki, Yoshitaka Araki

Journal:

Year:

1983

Language:

english

File:

PDF, 937 KB

english, 1983

107

Acid-catalyzed cyclization of vinylsilanes bearing a hydroxy group. Benzyldimethylsilyl group as an effective promoter and novel hydroxy surrogate

Katsukiyo Miura, Takeshi Hondo, Tatsuyuki Takahashi, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

2000

Language:

english

File:

PDF, 155 KB

english, 2000

108

Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst

Hajime Ito, Hiroshi Yamanaka, Jun-ichi Tateiwa, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

2000

Language:

english

File:

PDF, 244 KB

english, 2000

109

Synthesis and reactions of 2-cyclopropyl-2-propenyltrimethylsilane. Silicon-directed generation of cyclopropylcarbinyl system

Makoto Hojo, Katsufumi Ohsumi, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1992

Language:

english

File:

PDF, 124 KB

english, 1992

110

Stereoselective N-acylation of a new chiral auxiliary compound; 3-phenyl-l-menthopyrazole

Choji Kashima, Iwao Fukuchi, Katsumi Takahashi, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 254 KB

english, 1993

111

New access to Di-exo-methylenecyclobutanes via [2 + 2] cycloaddition of 3-methylthio-4-trimethylsilyl-1,2-butadiene with alkenes mediated by a Lewis acid

Makoto Hojo, Kyoji Tomita, Yoji Hirohara, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 255 KB

english, 1993

112

New access to carbonyl ylides by the silicon-based 1,3-elimination and their [3 + 2] cycloadditions to activated alkenes and alkynes: One-step synthesis of dihydrofurans and tetrahydrofurans

Makoto Hojo, Masakazu Ohkuma, Naruyasu Ishibashi, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 286 KB

english, 1993

113

A novel synthesis of 4-spirocyclopropyl β-lactams

Hiromu Aoyama, Hiroyuki Sagae, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 143 KB

english, 1993

114

Thermal isomerization of cyclopropyl-substituted silanes

Hideki Sakurai, Akira Hosomi, Makoto Kumada

Journal:

Tetrahedron Letters

Year:

1968

Language:

english

File:

PDF, 100 KB

english, 1968

115

2-Alkoxycarbonylallyltrimethylsilanes as new reagents of 2-alkoxycarbonylallylation of electrophiles

Akira Hosomi, Hidehiko Hashimoto, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 224 KB

english, 1980

116

Latent acetonylation of α,β -enones with allyltrimethylsilane or 2-methyl-2-propenyltrimethylsilane: synthesis of 1,5-diketones and annelation to fused cyclohexenones

Akira Hosomi, Hiroshi Kobayashi, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 255 KB

english, 1980

117

Synthesis and [3+2]cycloadditions of N-(trimethylsilylmethyl)isothioureas: a synthetic equivalent of novel 1,3-dipolar reagent, iminoazomethine ylid

Yoshinori Tominaga, Koichiro Ogata, Shinya Kohra, Makoto Hojo, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 300 KB

english, 1991

118

Tandem conjugate addition-aldol reaction to α,β-unsaturated esters and ketones using titanium amide

Akira Hosomi, Toshiharu Yanagi, Makoto Hojo

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 266 KB

english, 1991

119

Highly coordinate organosilicon compounds in synthesis: New entry to S,N-acetals by selective reduction of alkylthiomethyleniminium salts by use of trimethoxysilane and dilithium 2,3-butandiolate

Yoshinori Tominaga, Yoshiki Matsuoka, Hisashi Hayashida, Shinya Kohra, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 233 KB

english, 1988

120

Oxidative cleavage of silicon-carbon bond with trimethylamine-N-oxide. New access to primary alcohols and aldehydes from terminal alkenes and alkynes

Hideki Sakurai, Masatomo Ando, Nobuo Kawada, Kazuhiko Sato, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1986

Language:

english

File:

PDF, 128 KB

english, 1986

121

2-dimethylaminomethyl-3-trimethylsilylmethyl-1,3-butadiene as 2,2′-biallyl diradical synthon. A new and facile entry to 1,2-dimethylenecyclohexanes, and [6.6] and (6.7] ring systems

Akira Hosomi, Ken Otaka, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1986

Language:

english

File:

PDF, 237 KB

english, 1986

122

A convenient and novel synthesis of 1,1-dichloroalkenes using α-lithiated dichloromethyltrimethylsilane and aldehydes

Akira Hosomi, Masahiro Inaba, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1983

Language:

english

File:

PDF, 140 KB

english, 1983

123

A novel aminomethylation of silyl enol ethers with aminomethyl ethers catalyzed by iodotrimethylsilane or trimethylsilyl trifluoromethanesulfonate

Akira Hosomi, Susumu Iijima, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 224 KB

english, 1982

124

Highly regioselective diels-alder reactions of 2-trimethylsilylmethyl- 1,3-butadiene catalyzed by a lewis acid and applications to syntheses of terpenes

Akira Hosomi, Hirokazu Iguchi, Jun-ichi Sasaki, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 232 KB

english, 1982

125

Polyspiro disilacyclohexadienes a novel series of compounds showing spiroconjugation

Hideki Sakurai, Takeshi Koyama, Mitsuo Kira, Akira Hosomi, Yasuhiro Nakadaira

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 184 KB

english, 1982

126

Stepwise conversion of oxiranes to allylic alcohols by iodotrimethylsilane and DBU

Hideki Sakurai, Koshi Sasaki, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 243 KB

english, 1980

127

Alkylation and arylation of 2-trimethylsiloxyallyl halides. A new regiospecific route to silyl enol ethers

Hideki Sakurai, Akihiko Shirahata, Yoshitaka Araki, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1980

Language:

english

File:

PDF, 232 KB

english, 1980

128

2-Trimethylsilylethyl-1,3-butadiene as a synthetic equivalent of parent cross-conjugated hexatriene, 3-methylene-1,4-pentadiene

Akira Hosomi, Toshiyuki Masunari, Yoshinori Tominaga, Toshiharu Yanagi, Makoto Hojo

Journal:

Tetrahedron Letters

Year:

1990

Language:

english

File:

PDF, 262 KB

english, 1990

129

Regiospecific cycloaddition reactions using functionalized isoprenylsilane and related compounds

Akira Hosomi, Yasuyuki Sakata, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1985

Language:

english

File:

PDF, 224 KB

english, 1985

130

Highly stereoselective c-allylation of glycopyranosides with allylsilanes catalyzed by silyl triflate or iodosilane

Akira Hosomi, Yasuyuki Sakata, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1984

Language:

english

File:

PDF, 220 KB

english, 1984

131

Selective carbophilic addition of organolithiums to thioamides. A novel synthesis of unsymmetrical ketones and α-alkylated amines

Yoshinori Tominaga, Shinya Kohra, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1987

Language:

english

File:

PDF, 251 KB

english, 1987

132

Preparation of cyclopropylmethyl ketones from 3-butenylsilane and acid chloride

Hideki Sakurai, Takafumi Imai, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1977

Language:

english

File:

PDF, 235 KB

english, 1977

133

Silyl radicals IV : Homolytic aromatic silylations with hydrosilanes

Hideki Sakurai, Akira Hosomi, Makoto Kumada

Journal:

Tetrahedron Letters

Year:

1969

Language:

english

File:

PDF, 98 KB

english, 1969

134

Silyl radicals V : Novel cyclization reactions involving homolytic aromatic silylation

Hideki Sakurai, Akira Hosomi, Makoto Kumada

Journal:

Tetrahedron Letters

Year:

1969

Language:

english

File:

PDF, 193 KB

english, 1969

135

2-trimethylsilylmethyl-1,3-butadiene as a novel reagent for isoprenylation. New access to ipsenol and ipsdienol, pheromones of Ips paraconfusus

Akira Hosomi, Masaki Saito, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1979

Language:

english

File:

PDF, 238 KB

english, 1979

136

Synthesis of α,α-dimethylallylsilanes, a reagent of regiospecific prenylation of acetals and carbonyl compounds

Akira Hosomi, Hideki Sakurai

Journal:

Tetrahedron Letters

Year:

1978

Language:

english

File:

PDF, 224 KB

english, 1978

137

Titanocene- and zirconocene-mediated cyclization of allyl propargyl ethers. Stereoselective synthesis of 3-methylenetetrahydrofurans

Katsukiyo Miura, Masashi Funatsu, Hiroshi Saito, Hajime Ito, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 251 KB

english, 1996

138

“Tailor-Made” carbonyl ylides: [3 + 2] cycloaddition of the parent and optionally substituted nonstabilized carbonyl ylides

Makoto Hojo, Hidenori Aihara, Hajime Ito, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 311 KB

english, 1996

139

Direct alkynyl group transfer from silicon to copper: New preparation method of alkynylcopper (I) reagents

Hajime Ito, Kikuo Arimoto, Hiro-omi Sensul, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1997

Language:

english

File:

PDF, 205 KB

english, 1997

140

Lewis acid-promoted addition of methylenecyclopropanes to aldehydes and ketones

Katsukiyo Miura, Mizuki Takasumi, Takeshi Hondo, Hiroshi Saito, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1997

Language:

english

File:

PDF, 242 KB

english, 1997

141

Selective O-acylation of silyl enol ethers with acid halides mediated by a copper(I) salt

Hajime Ito, Tomoko Ishizuka, Jun-ichi Tateiwa, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 190 KB

english, 1998

142

New reactivity of methoxyhydridosilane in the catalytic activation system

Makoto Hojo, Chikara Murakami, Atsuko Fujii, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 215 KB

english, 1999

143

An unprecedented catalytic reaction using gold(I) complexes

Hajime Ito, Tatsuki Yajima, Jun-ichi Tateiwa, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 242 KB

english, 1999

144

Homolytic allylation of vinyl iodides with allylstananes

Katsukiyo Miura, Hiroshi Saito, Daisuke Itoh, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 222 KB

english, 1999

145

Characterization of vps33+, a gene required for vacuolar biogenesis and protein sorting in Schizosaccharomyces pombe

Tomoko Iwaki, Fumi Osawa, Masayuki Onishi, Takako Koga, Yasuko Fujita, Akira Hosomi, Naotaka Tanaka, Yasuhisa Fukui, Kaoru Takegawa

Journal:

Year:

2003

Language:

english

File:

PDF, 358 KB

english, 2003

146

Thegld1+gene encoding glycerol dehydrogenase is required for glycerol metabolism inSchizosaccharomyces pombe

Tomohiko Matsuzawa, Takao Ohashi, Akira Hosomi, Naotaka Tanaka, Hideki Tohda, Kaoru Takegawa

Journal:

Applied Microbiology and Biotechnology

Year:

2010

Language:

english

File:

PDF, 530 KB

english, 2010

147

Enantiomerically enriched preparation of enolizable β-keto amides. Diastereoselective α-acylation and subsequent aminolysis of 2-acyl-3-phenyl-l-menthopyrazoles

Choji Kashima, Iwao Fukuchi, Katsumi Takahashi, Akira Hosomi

Journal:

Year:

1996

Language:

english

File:

PDF, 586 KB

english, 1996

148

Regiospecific allylation of acetals with allylsilanes catalyzed by iodotrimethylsilane. Synthesis of homoallylethers

Hideki Sakurai, Koshi Sasaki, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1981

Language:

english

File:

PDF, 244 KB

english, 1981

149

Pentaco—ordinate organosilicon compounds in synthesis: Asymmetric reduction of carbonyl compounds with hydrosilanes catalyzed by chiral bases

Shinya Kohra, Hisashi Hayashida, Yoshinori Tominaga, Akira Hosomi

Journal:

Tetrahedron Letters

Year:

1988

Language:

english

File:

PDF, 257 KB

english, 1988

150

Chemistry of organosilicon compounds : LXXI. Ring closure of (4-pentenyl)hydrosilanes by intramolecular hydrosilylation with transition metal salts

Hideki Sakurai, Toshifumi Hirose, Akira Hosomi

Journal:

Journal of Organometallic Chemistry

Year:

1975

Language:

english

File:

PDF, 416 KB

english, 1975

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