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101

Mechanistic Studies of Pd-Catalyzed Regioselective Aryl CH Bond Functionalization with Strained Alkenes: Origin of Regioselectivity

Dr. David I. Chai, Dr. Praew Thansandote, Prof. Dr. Mark Lautens

Journal:

Chemistry - A European Journal

Year:

2011

Language:

english

File:

PDF, 632 KB

english, 2011

102

ChemInform Abstract: Transition Metal Catalyzed Stereospecific Intramolecular (3 + 2) Cycloadditions of Methylenecyclopropanes with Alkynes.

M. LAUTENS, Y. REN

Journal:

Year:

1997

File:

PDF, 33 KB

1997

103

ChemInform Abstract: Palladium-Catalyzed Intramolecular (3 + 2) Cycloadditions of Methylenecyclopropanes with Alkenes: Diastereomeric Methylenecyclopropanes Exhibit Complementary Facial Selectivity.

M. LAUTENS, Y. REN

Journal:

Year:

1997

File:

PDF, 30 KB

1997

104

ChemInform Abstract: Diastereoselective Intermolecular (4 + 3) Cycloadditions via an Extended Transition State: A Route to Enantiomerically Enriched Cycloadducts.

M. LAUTENS, R. ASPIOTIS, J. COLUCCI

Journal:

Year:

1997

File:

PDF, 30 KB

1997

105

ChemInform Abstract: Nickel-Catalyzed Addition of Grignard Reagents to Oxabicyclic Compounds. Ring-Opening Reactions with Previously Unreactive Substrates and Nucleophiles.

M. LAUTENS, S. MA

Journal:

Year:

1997

File:

PDF, 33 KB

1997

106

ChemInform Abstract: Ring Opening in the Hydrostannation of Methylenecyclopropanes: Effect of the Catalyst and Substrate.

M. LAUTENS, C. MEYER, A. LORENZ

Journal:

Year:

1997

File:

PDF, 29 KB

1997

107

ChemInform Abstract: New Strategy for the Stereocontrolled Construction of Decalins and Fused Polycycles via a Tandem Diels-Alder Ring-Opening Sequence.

M. LAUTENS, E. FILLION

Journal:

Year:

1997

File:

PDF, 34 KB

1997

108

ChemInform Abstract: Synthesis of Highly Functionalized Diquinanes by the Regio- and Stereoselective Cleavage of Homo-Diels-Alder Cycloadducts.

M. LAUTENS, W. TAM, J. BLACKWELL

Journal:

Year:

1997

File:

PDF, 34 KB

1997

109

ChemInform Abstract: Synthesis and Reactions of 1,2-Disubstituted Methylenecyclopropanes Prepared via Intramolecular Cyclopropanation of Allenic Diazoacetates.

M. LAUTENS, C. MEYER, A. VAN OEVEREN

Journal:

Year:

1997

File:

PDF, 35 KB

1997

110

ChemInform Abstract: (cis-1-Cyclohexyl-6-methylene-3,5,6,6a-tetrahydro-1H-cyclopenta(c) furan-4-yl)-methyl 3,5-Dinitrobenzoate.

M. LAUTENS, A. J. LOUGH, Y. REN

Journal:

Year:

1997

File:

PDF, 25 KB

1997

111

ChemInform Abstract: Synthesis of Cyclohexenols and Cycloheptenols via the Regioselective Reductive Ring Opening of Oxabicyclic Compounds.

M. LAUTENS, S. MA, P. CHIU

Journal:

Year:

1997

File:

PDF, 32 KB

1997

112

ChemInform Abstract: An Expedient Route for the Stereoselective Construction of Bridged Polyheterocyclic Ring Systems Using the Tandem “Pincer” Diels-Alder Reaction.

M. LAUTENS, E. FILLION

Journal:

Year:

1997

File:

PDF, 34 KB

1997

113

ChemInform Abstract: Regioselective Hydrostannation of Allenes Catalyzed by Pd(OH)2/C.

M. LAUTENS, D. OSTROVSKY, B. TAO

Journal:

Year:

1997

File:

PDF, 29 KB

1997

114

ChemInform Abstract: Using Ring-Opening Reactions of Oxabicyclic Compounds as a Strategy in Organic Synthesis

P. CHIU, M. LAUTENS

Journal:

Year:

1997

File:

PDF, 24 KB

1997

115

ChemInform Abstract: General Strategy Toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline.

M. LAUTENS, T. ROVIS

Journal:

Year:

1997

File:

PDF, 30 KB

1997

116

ChemInform Abstract: Base-Induced Ring Opening of Aza- and Thiaoxa[3.2.1] and -[3.3.1]bicycles as an Enantioselective Approach to Azepines, Thiepines, and Thiocines.

M. LAUTENS, E. FILLION, M. SAMPAT

Journal:

Year:

1998

File:

PDF, 32 KB

1998

117

ChemInform Abstract: A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes.

M. LAUTENS, T. ROVIS

Journal:

Year:

1998

File:

PDF, 35 KB

1998

118

ChemInform Abstract: Palladium-Catalyzed Hydrostannation—Cyclization of 1,6-Diynes. Generation of 1,2-Dialkylidenecyclopentanes with a Tributylstannane Moiety.

M. LAUTENS, N. D. SMITH, D. OSTROVSKY

Journal:

Year:

1998

File:

PDF, 33 KB

1998

119

ChemInform Abstract: The Effect of the Acidifying Group on the Regioselectivity of the Base-Induced Ring Opening of Hetero-oxabicyclic [3.2.1] and [3.3.1] Systems.

M. LAUTENS, E. FILLION, M. SAMPAT

Journal:

Year:

1998

File:

PDF, 33 KB

1998

120

ChemInform Abstract: Scope of the Nickel Catalyzed Asymmetric Reductive Ring Opening Reaction. Synthesis of Enantiomerically Enriched Cyclohexenols.

M. LAUTENS, T. ROVIS

Journal:

Year:

1998

File:

PDF, 40 KB

1998

121

ChemInform Abstract: Exploring the Reactivity of Dioxacyclic Compounds as a Route to Polysubstituted Decalins and Fused Polycycles.

M. LAUTENS, E. FILLION

Journal:

Year:

1998

File:

PDF, 42 KB

1998

122

ChemInform Abstract: The Utility of the Homo Diels—Alder Reaction in the Synthesis of Natural Product Skeletons: A Cycloaddition—Fragmentation—Cyclization Sequence to Diquinanes and Triquinanes.

M. LAUTENS, J. BLACKWELL

Journal:

Year:

1998

File:

PDF, 39 KB

1998

123

ChemInform Abstract: Asymmetric Synthesis of Bryostatin 2.

D. A. EVANS, P. H. CARTER, E. M. CARREIRA, J. A. PRUNET, A. B. CHARETTE, M. LAUTENS

Journal:

Year:

1999

File:

PDF, 25 KB

1999

124

ChemInform Abstract: Diastereoselective Ring Closing Metathesis Reactions: Synthesis of Bicyclic Diallylic Alcohols and Ethers.

Mark Lautens, Gregory Hughes

Journal:

Year:

1999

File:

PDF, 33 KB

1999

125

ChemInform Abstract: Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline.

Mark Lautens, Tomislav Rovis

Journal:

Year:

1999

File:

PDF, 30 KB

1999

126

ChemInform Abstract: Total Synthesis of Bryostatin 2.

David A. Evans, Percy H. Carter, Erick M. Carreira, Andre B. Charette, Joelle A. Prunet, Mark Lautens

Journal:

Year:

1999

File:

PDF, 25 KB

1999

127

ChemInform Abstract: Cerium(III) Chloride Promoted Opening of [3.2.1]Oxabicycles with Methyllithium.

Mark Lautens, Oscar de Frutos, Timothy A. Stammers

Journal:

Year:

2000

Language:

english

File:

PDF, 35 KB

english, 2000

128

ChemInform Abstract: Use of γ-Carboxy-α,β-unsaturated Aldehydes as Synthetic Equivalents of β,γ-Unsaturated Aldehydes in a Novel Stereoselective Approach to Diketides.

Gregory Hughes, Mark Lautens, Chuck Wen

Journal:

Year:

2000

File:

PDF, 31 KB

2000

129

ChemInform Abstract: Allylic Substitution Reactions

Andreas Pfaltz, Mark Lautens

Journal:

Year:

2000

File:

PDF, 24 KB

2000

130

ChemInform Abstract: Hydroalumination of Carbon—Carbon Double Bonds

Mark Lautens, Tomislav Rovis

Journal:

Year:

2000

File:

PDF, 24 KB

2000

131

ChemInform Abstract: Palladium-Catalyzed Enantioselective Alkylative Ring Opening.

Mark Lautens, Jean-Luc Renaud, Sheldon Hiebert

Journal:

Year:

2000

File:

PDF, 34 KB

2000

132

ChemInform Abstract: A New Route to Fused Aromatic Compounds by Using a Palladium-Catalyzed Alkylation—Alkenylation Sequence.

Mark Lautens, Sandrine Piguel

Journal:

Year:

2000

File:

PDF, 31 KB

2000

133

ChemInform Abstract: Synthetic Studies of the Formation of Oxazoles and Isoxazoles from N-Acetoacetyl Derivatives: Scope and Limitations.

Mark Lautens, Amelie Roy

Journal:

Year:

2000

File:

PDF, 34 KB

2000

134

ChemInform Abstract: Formation of Homoallyl Stannanes via Palladium-Catalyzed Stannylative Cyclization of Enynes.

Mark Lautens, John Mancuso

Journal:

Year:

2000

File:

PDF, 29 KB

2000

135

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Phenols.

Mark Lautens, Keith Fagnou, Mark Taylor

Journal:

Year:

2000

File:

PDF, 33 KB

2000

136

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon—Heteroatom Bond Forming Process.

Mark Lautens, Keith Fagnou, Tomislav Rovis

Journal:

Year:

2000

File:

PDF, 32 KB

2000

137

ChemInform Abstract: The Use of 1,4-Dichlorobut-2-ene as a Synthetic Equivalent of 4-Bromobut-1-ene.

Gregory Hughes, Mark Lautens, Jingxiao Wu

Journal:

Year:

2000

File:

PDF, 31 KB

2000

138

ChemInform Abstract: Enantioselective Ring Opening of Aza and Oxabicyclic Alkenes with Dimethylzinc.

Mark Lautens, Sheldon Hiebert, Jean-Luc Renaud

Journal:

Year:

2000

File:

PDF, 37 KB

2000

139

ChemInform Abstract: Metal-Catalyzed Hydrostannations

Nicholas D. Smith, John Mancuso, Mark Lautens

Journal:

Year:

2000

File:

PDF, 23 KB

2000

140

ChemInform Abstract: Rhodium-Catalyzed Ring Opening of Vinyl Epoxides with Alcohols and Aromatic Amines.

Keith Fagnou, Mark Lautens

Journal:

Year:

2000

File:

PDF, 31 KB

2000

141

ChemInform Abstract: Diastereoselective Double Ring Closing Metathesis Reactions as an Approach to Symmetrical Bicyclodienes.

Mark Lautens, Gregory Hughes, Valentin Zunic

Journal:

Year:

2000

File:

PDF, 38 KB

2000

142

ChemInform Abstract: Amphoteric Character of 2-Vinyloxiranes: Synthetic Equivalents of β,γ-Unsaturated Aldehydes and a Vinylogous Enolate.

Mark Lautens, Stephane G. Ouellet, Stephane Raeppel

Journal:

Year:

2001

File:

PDF, 34 KB

2001

143

ChemInform Abstract: Practical Synthesis of Acetophenones from Phenoltriflates.

Fabrice Garrido, Stephane Raeppel, Andre Mann, Mark Lautens

Journal:

Year:

2001

File:

PDF, 26 KB

2001

144

ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles.

Mark Lautens, Keith Fagnou, Mark Taylor, Tomislav Rovis

Journal:

Year:

2001

File:

PDF, 32 KB

2001

145

ChemInform Abstract: Rhodium-Catalyzed Coupling Reactions of Arylboronic Acids to Olefins in Aqueous Media.

Mark Lautens, Amelie Roy, Koichiro Fukuoka, Keith Fagnou, Belen Martin-Matute

Journal:

Year:

2001

File:

PDF, 31 KB

2001

146

ChemInform Abstract: Mechanistic Studies of the Palladium-Catalyzed Ring Opening of Oxabicyclic Alkenes with Dialkylzinc.

Mark Lautens, Sheldon Hiebert, Jean-Luc Renaud

Journal:

Year:

2001

File:

PDF, 24 KB

2001

147

ChemInform Abstract: Effects of Halide Ligands and Protic Additives on Enantioselectivity and Reactivity in Rhodium-Catalyzed Asymmetric Ring-Opening Reactions.

Mark Lautens, Keith Fagnou

Journal:

Year:

2001

Language:

english

File:

PDF, 40 KB

english, 2001

148

ChemInform Abstract: Halide Effects in Transition Metal Catalysis

Keith Fagnou, Mark Lautens

Journal:

Year:

2002

File:

PDF, 23 KB

2002

149

ChemInform Abstract: Enantioselective Allylation of β,γ-Unsaturated Aldehydes Generated via Lewis Acid Induced Rearrangement of 2-Vinyloxiranes.

Mark Lautens, Matthew L. Maddess, Effiette L. O. Sauer, Stephane G. Ouellet

Journal:

Year:

2002

File:

PDF, 38 KB

2002

150

ChemInform Abstract: Palladium-Catalyzed Sequential Alkylation—Alkenylation Reactions and Their Application to the Synthesis of Fused Aromatic Rings.

Mark Lautens, Jean-Francois Paquin, Sandrine Piguel, Marc Dahlmann

Journal:

Year:

2002

File:

PDF, 33 KB

2002