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51

ChemInform Abstract: Ethylzincation of Monosubstituted Alkenes Catalyzed by EtMgBr—Cl2ZrCp2 and Palladium-Catalyzed Cross Coupling of the Resultant Diisoalkylzinc Derivatives.

Sebastien Gagneur, Jean-Luc Montchamp, Ei-ichi Negishi

Journal:

Year:

2000

File:

PDF, 36 KB

2000

52

ChemInform Abstract: Asymmetric Carbometalations

Ei-Ichi Negishi

Journal:

Year:

2001

File:

PDF, 22 KB

2001

53

ChemInform Abstract: A Strictly “Pair”-Selective Synthesis of Conjugated Diynes via Pd-Catalyzed Cross Coupling of 1,3-Diynylzincs: A Superior Alternative to the Cadiot-Chodkiewicz Reaction.

Ei-ichi Negishi, Mitsuhiro Hata, Caiding Xu

Journal:

Year:

2001

File:

PDF, 32 KB

2001

54

ChemInform Abstract: Strictly Regiocontrolled α-Monosubstitution of Cyclic Carbonyl Compounds with Alkynyl and Alkyl Groups via Pd-Catalyzed Coupling of Cyclic α-Iodoenones with Organozincs.

Ei-ichi Negishi, Ze Tan, Show-Yee Liou, Baiqiao Liao

Journal:

Year:

2001

Language:

english

File:

PDF, 43 KB

english, 2001

55

ChemInform Abstract: A Novel Hydrogen Transfer Hydroalumination of Alkenes with Triisobutylaluminum Catalyzed by Pd and Other Late Transition Metal Complexes.

Sebastien Gagneur, Hidefumi Makabe, Ei-ichi Negishi

Journal:

Year:

2001

File:

PDF, 29 KB

2001

56

ChemInform Abstract: Some Newer Aspects of Organozirconium Chemistry of Relevance to Organic Synthesis: Zr-Catalyzed Enantioselective Carbometalation

Ei-Ichi Negishi

Journal:

Year:

2001

File:

PDF, 24 KB

2001

57

ChemInform Abstract: Highly Satisfactory Procedures for the Pd-Catalyzed Cross Coupling of Aryl Electrophiles with in situ Generated Alkynylzinc Derivatives.

Luigi Anastasia, Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 29 KB

2002

58

ChemInform Abstract: A Convenient and Asymmetric Protocol for the Synthesis of Natural Products Containing Chiral Alkyl Chains via Zr-Catalyzed Asymmetric Carboalumination of Alkenes. Synthesis of Phytol and Vitamins E and K.

Shouquan Huo, Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 34 KB

2002

59

ChemInform Abstract: Stereoselective Synthesis of Exocyclic Alkenes by Cu-Catalyzed Allylmagnesiation, Pd-Catalyzed Alkylation, and Ru-Catalyzed Ring-Closing Metathesis: Highly Stereoselective Synthesis of (Z)-(V) and (E)-(IX)-γ-Bisabolenes.

Luigi Anastasia, Yves R. Dumond, Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 33 KB

2002

60

ChemInform Abstract: A Highly Efficient, Selective, and General Method for the Synthesis of Conjugated (all-E)-Oligoenes of the (CH=CH)n Type via Iterative Hydrozirconation—Palladium-Catalyzed Cross-Coupling.

Fanxing Zeng, Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 37 KB

2002

61

A Genealogy of Pd-Catalyzed Cross-Coupling.

Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 24 KB

2002

62

Catalytic and Selective Conversion of (Z)-2-En-4-ynoic Acids to Either 2H-Pyran-2-ones in the Presence of ZnBr2 or (Z)-5-Alkylidenefuran-2(5H)-ones in the Presence of Ag2CO3.

Luigi Anastasia, Caiding Xu, Ei-ichi Negishi

Journal:

Year:

2002

File:

PDF, 32 KB

2002

63

Synthesis of Natural Products via Nucleophilic Attack on σ,π-Ligands of Palladium—Alkene, Palladium—Alkyne, and Related σ,π-Complexes

Caiding Xu, Ei-Ichi Negishi

Journal:

Year:

2003

File:

PDF, 60 KB

2003

64

Synthesis of Natural Products via Palladium-Catalyzed Cross-Coupling

Ze Tan, Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 56 KB

2003

65

Palladium-Catalyzed Allylation and Related Substitution Reactions of Enolates and Related Derivatives of “Ordinary” Ketones, Aldehydes, and Other Carbonyl Compounds

Ei-Ichi Negishi, Show-Yee Liou

Journal:

Year:

2003

File:

PDF, 58 KB

2003

66

Palladium Complexes Containing Halogen and Oxygen Ligands

Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 56 KB

2003

67

Palladium-Catalyzed Aryl—Aryl Coupling

Luigi Anastasia, Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 49 KB

2003

68

Palladium-Catalyzed Hydrometallation

Hidefumi Makabe, Ei-Ichi Negishi

Journal:

Year:

2003

File:

PDF, 49 KB

2003

69

Palladium-Catalyzed Isomerization of Alkenes, Alkynes, and Related Compounds without Skeletal Rearrangements

Ei-Ichi Negishi

Journal:

Year:

2003

File:

PDF, 52 KB

2003

70

Palladium-Catalyzed Hydrogenation: Palladium-Catalyzed Heterogeneous Hydrogenation

Anthony O. King, Robert D. Larsen, Ei-Ichi Negishi

Journal:

Year:

2003

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PDF, 50 KB

2003

71

Palladium-Catalyzed Carbon Skeletal Rearrangements Other than [3,3] Rearrangements

Ei-Ichi Negishi

Journal:

Year:

2003

File:

PDF, 51 KB

2003

72

Acylpalladation and Related Addition Reactions—Intramolecular Acylpalladation: Intramolecular Acylpalladation Reactions with Alkenes, Alkynes, and Related Unsaturated Compounds

Christophe Coperet, Ei-Ichi Negishi

Journal:

Year:

2003

File:

PDF, 49 KB

2003

73

Other Palladium-Catalyzed or -Promoted Oxidation Reactions via 1,2-or 1,4-Elimination

Yuzo Fujiwara, Ei-Ichi Negishi

Journal:

Year:

2003

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PDF, 51 KB

2003

74

Other Miscellaneous Palladium-Catalyzed or -Promoted Oxidation Reactions

Ei-Ichi Negishi

Journal:

Year:

2003

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PDF, 50 KB

2003

75

Historical Background of Organopalladium Chemistry

Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 50 KB

2003

76

Organopalladium Compounds Containing Pd(0) and Pd(II). General Discussion of the Methods of Synthesis and in situ Generation of Organopalladium Compounds

Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 51 KB

2003

77

Palladium-Catalyzed Alkenyl—Aryl, Aryl—Alkenyl, and Alkenyl—Alkenyl Coupling Reactions

Shouquan Huo, Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 51 KB

2003

78

Pd(0) and Pd(II) Complexes Containing Phosphorus and Other Group 15 Atom Ligands

Daniele Choueiry, Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 52 KB

2003

79

Palladium-Catalyzed Alkynylation

Ei-ichi Negishi, Luigi Anastasia

Journal:

Year:

2003

File:

PDF, 50 KB

2003

80

Palladium-Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1-Disubstituted Alkenes Terminated by Carbonylative Reactions

Ei-ichi Negishi, Christophe Coperet

Journal:

Year:

2003

File:

PDF, 70 KB

2003

81

Palladium-Catalyzed Cross-Coupling Involving β-hetero-Substituted Compounds. Palladium-Catalyzed α-Substitution Reactions of Enolates and Related Derivatives Other than the Tsuji—Trost Allylation Reaction

Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 72 KB

2003

82

Palladium-Catalyzed Cross-Coupling Involving β-hetero- Substituted Compounds Other than Enolates

Ei-ichi Negishi, Asaf Alimardanov

Journal:

Year:

2003

File:

PDF, 71 KB

2003

83

Palladium-Catalyzed Cross-Coupling Substitution

Ei-ichi Negishi, Yves Dumond

Journal:

Year:

2003

File:

PDF, 68 KB

2003

84

Reactions Between Homoallyl-, and Homopropargyl-, or Homobenzyl and Alkenyl or Aryl Electrophiles

Ei-ichi Negishi, Fanxing Zeng

Journal:

Year:

2003

File:

PDF, 69 KB

2003

85

Palladium-Catalyzed Cross-Coupling Involving Alkylmetals or Alkyl Electrophiles

Ei-ichi Negishi, Sebastien Gagneur

Journal:

Year:

2003

File:

PDF, 69 KB

2003

86

Palladium-Catalyzed Alkynylation with Alkynylmetals and Alkynyl Electrophiles

Ei-ichi Negishi, Caiding Xu

Journal:

Year:

2003

File:

PDF, 52 KB

2003

87

Palladium-Catalyzed Cross-Coupling Between Allyl, Benzyl, or Propargyl Groups and Unsaturated Groups

Ei-ichi Negishi, Fang Liu

Journal:

Year:

2003

File:

PDF, 52 KB

2003

88

Palladium-Catalyzed Cross-Coupling Between Allyl-, Benzyl, or Propargylmetals and Allyl, Benzyl, or Propargyl Electrophiles

Ei-ichi Negishi, Baiqiao Liao

Journal:

Year:

2003

File:

PDF, 51 KB

2003

89

Palladium-Catalyzed Carbon—Carbon Cross-Coupling. Overview of the Negishi Protocol with Zn, Al, Zr, and Related Metals

Ei-ichi Negishi

Journal:

Year:

2003

File:

PDF, 53 KB

2003

90

Highly Satisfactory Alkynylation of Alkenyl Halides via Pd-Catalyzed Cross-Coupling with Alkynylzincs and Its Critical Comparison with the Sonogashira Alkynylation.

Ei-ichi Negishi, Mingxing Qian, Fanxing Zeng, Luigi Anastasia, David Babinski

Journal:

Year:

2003

Language:

english

File:

PDF, 235 KB

english, 2003

91

Highly Selective Synthesis of (E)-3-Methyl-1-trialkylsilyl-3-en-1-ynes via trans-Selective Alkynylation Catalyzed by Cl2Pd(DPEphos) and Stereospecific Methylation with Methylzincs Catalyzed by Pd(tBu3P)2.

Ji-cheng Shi, Xingzhong Zeng, Ei-ichi Negishi

Journal:

Year:

2003

Language:

english

File:

PDF, 287 KB

english, 2003

92

Synthesis and Reactivity Zirconocene Derivatives

Ei-Ichi Negishi, Shouquan Huo

Journal:

Year:

2004

File:

PDF, 53 KB

2004

93

Pd-Catalyzed Selective Tandem Arylation—Alkylation of 1,1-Dihalo-1-alkenes with Aryl- and Alkylzinc Derivatives to Produce α-Alkyl-substituted Styrene Derivatives.

Ji-cheng Shi, Ei-ichi Negishi

Journal:

Year:

2004

File:

PDF, 208 KB

2004

94

Highly Stereoselective Synthesis of (1E)-2-Methyl-1,3-dienes by Palladium-Catalyzed trans-Selective Cross-Coupling of 1,1-Dibromo-1-alkenes with Alkenylzinc Reagents.

Xingzhong Zeng, Mingxing Qian, Qian Hu, Ei-ichi Negishi

Journal:

Year:

2004

File:

PDF, 147 KB

2004

95

Use of InCl3 as a Cocatalyst and a Cl2Pd(DPEphos)—P(2-Furyl)3 Catalyst System for One-Pot Hydrometalation—Cross-Coupling and Carbometalation—Cross-Coupling Tandem Processes.

Mingxing Qian, Zhihong Huang, Ei-ichi Negishi

Journal:

Year:

2004

File:

PDF, 131 KB

2004

96

An Efficient and General Method for the Synthesis of α,ω-Difunctional Reduced Polypropionates by Zr-Catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Side Chain (I).

Ze Tan, Ei-ichi Negishi

Journal:

Year:

2004

File:

PDF, 63 KB

2004

97

Efficient and Selective Synthesis of 6,7-Dehydrostipiamide via Zr-Catalyzed Asymmetric Carboalumination and Pd-Catalyzed Cross-Coupling of Organozincs

Xingzhong Zeng, Fanxing Zeng, Ei-ichi Negishi

Journal:

Year:

2004

File:

PDF, 10 KB

2004

98

Palladium-Catalyzed Cross-Coupling Reactions with Zinc, Boron, and Indium Exhibiting High Turnover Numbers (TONs): Use of Bidentate Phosphines and Other Critical Factors in Achieving High TONs.

Zhihong Huang, Mingxing Qian, David J. Babinski, Ei-ichi Negishi

Journal:

Year:

2005

File:

PDF, 30 KB

2005

99

Palladium- or Nickel-Catalyzed Cross-Coupling with Organometals Containing Zinc, Aluminum, and Zirconium: The Negishi Coupling

Ei-ichi Negishi, Xingzhong Zeng, Ze Tan, Mingxing Qian, Qian Hu, Zhihong Huang

Journal:

Year:

2005

File:

PDF, 8 KB

2005

100

Palladium-Catalyzed Cross-Coupling Reaction of Alkynylzincs with Benzylic Electrophiles.

Mingxing Qian, Ei-ichi Negishi

Journal:

Year:

2005

File:

PDF, 18 KB

2005