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Gold(I)-Catalyzed Claisen Rearrangement of Allenyl Vinyl Ethers: Missing Transition States Revealed through Evolution of Aromaticity, Au(I) as an Oxophilic Lewis Acid, and Lower Energy Barriers from a High Energy Complex
Vidhani, Dinesh V., Cran, John W., Krafft, Marie E., Manoharan, Mariappan, Alabugin, Igor V.Volume:
78
Language:
english
Journal:
The Journal of Organic Chemistry
DOI:
10.1021/jo302152j
Date:
March, 2013
File:
PDF, 4.08 MB
english, 2013