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Deprotonation of arylnitromethanes. Higher intrinsic rate constants with thiolate ions than with oxyanions or amines as the proton acceptors. Hydrogen bonding in the transition state and desolvation of the base as competing factors in proton transfer at carbon
Bernasconi, Claude F., Wiersema, Derk, Stronach, Michael W.Volume:
58
Language:
english
Journal:
The Journal of Organic Chemistry
DOI:
10.1021/jo00053a039
Date:
January, 1993
File:
PDF, 830 KB
english, 1993