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Sterically crowded diphosphinomethane ligands: molecular structures, UV-photoelectron spectroscopy and a convenient general synthesis of tBu2PCH2PtBu2 and related speciesDedicated to Professor Roald Hoffmann on the occasion of his 65th birthday.Electronic supplementary information (ESI) available: photoelectron spectra for compounds 1–6, ORTEP diagrams for compounds 1–3 and 5–9+, calculated minimum structures (UB3LYP/6-31G**) and structural parameters for two forms of the radical cation dmpm. See http://www.rsc.org/suppdata/nj/b2/b210114a/
Eisenträger, Frank, Göthlich, Alexander, Gruber, Irene, Heiss, Helmut, Kiener, Christoph A., Krüger, Carl, Ulrich Notheis, J., Rominger, Frank, Scherhag, Gunter, Schultz, Madeleine, Straub, Bernd F.,Volume:
27
Language:
english
Journal:
New Journal of Chemistry
DOI:
10.1039/b210114a
Date:
February, 2003
File:
PDF, 376 KB
english, 2003