Cesium dithiolate based syntheses of keto-functionalized thio-crown ethers employing the novel building block 1,3-dimercaptoacetone. Molecular structures of 2,5,9,12-tetrathia-7-oxo(13)-m-benzenophane and 1,4,7,10,13-pentathiacyclohexadecan-15-one. [Erratum to document cited in CA120:77269]

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