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Intramolecular, base-induced formation of a metal-metal bond in [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2]3+ (L = 1,4,7-trimethyl-1,4,7-triazacyclononane). Crystal structures of [L2MoIII2(.mu.-OH)(.mu.-CH3CO2)2](ClO4)3.cntdot.H2O and [L2MoIII2(.mu.-O)(.mu.-CH3CO2)2](ClO4)(BF4).cntdot.H2O and of the mixed-valence complex [L2MoIIIMoIV(.mu.-O)(.mu.-CH3CO2)2](ClO43.cntdot.H2O
Wieghardt, Karl, Bossek, Ursula, Neves, Ademir, Nuber, Bernhard, Weiss, JohannesVolume:
28
Language:
english
Journal:
Inorganic Chemistry
DOI:
10.1021/ic00302a013
Date:
February, 1989
File:
PDF, 1.13 MB
english, 1989