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Stereochemical investigation of three 47-electron clusters in the homologous 48/47-electron [Co3(.eta.5-C5Me5)3-x(.eta.5-C5H4Me)x(.mu.3-CO)(.mu.3-NH)]n series (x = 0, 1, 2: n = 0, +1): bonding analysis of redox-generated changes in geometry upon formation of electron-deficient species by oxidation of triangularly bonded 48-electron metal clusters containing .pi.-acceptor carbonyl capping ligands
Ziebarth, Michael S., Dahl, Lawrence F.Volume:
112
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00162a052
Date:
March, 1990
File:
PDF, 1.15 MB
english, 1990