Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os 3 (CO) 10 (dppm) to HOs 3 (CO) 8 [μ-PhP(C 6 H 4 -μ 2 ,η 1 )CH 2 PPh 2 ]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster
Huang, Shih-Huang, Keith, Jason M., Hall, Michael B., Richmond, Michael G.Volume:
29
Language:
english
Journal:
Organometallics
DOI:
10.1021/om100475v
Date:
September, 2010
File:
PDF, 3.62 MB
english, 2010