First examples of an isomeric methylene-bridged free phosphinomethylphosphoranimine and a metalated phosphinomethylphosphoranimine. Synthesis, characterization, and isomerization of the heterodifunctional ligand Me3SiN:P(Ph)2CH2PPh2 and the transmetalation to the titanium derivative (.eta.5-C5H5)Ti(Cl)2N:P(Ph)2CH2PPh2

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