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Effect of polyfluorination on ring inversion barriers for cyclooctatetraenes. Transition-metal compounds of unsaturated, polyfluorinated cycloaliphatics. Crystal and molecular structures of [Fe(.eta.-C5R5)(.eta.1-heptafluorocycloocta-1,3,5,7-tetraenyl)(CO)2] (R = H, Me), {[Fe(.eta.-C5H5)(CO)2]2(.mu.2-(1.eta.,5.eta.)-hexafluorocycloocta-1,3,5,7-tetraenediyl)], and [Mn((3.eta.)-heptafluorotricyclo[4.2.0.02,5]octa-3,7-dienyl)(CO)5]
Hughes, Russell P., Carl, Richard T., Doig, Stephen J., Hemond, Richard C., Samkoff, Deborah E., Smith, Wayne L., Stewart, Leslie C., Davis, Raymond E., Holland, Katherine D.Volume:
9
Language:
english
Journal:
Organometallics
DOI:
10.1021/om00160a022
Date:
October, 1990
File:
PDF, 1.69 MB
english, 1990