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Synthesis, stereochemical analysis, and ligand-transformation reactions of new classes of bicapped tricobalt clusters, [Co3(.eta.5-C5H5-xMex)3(.mu.3-X)(.mu.3-Y)]n (x = 0, 1, 5), containing mixed .pi.-acceptor X and .pi.-donor Y capping ligands (X = CO, NO; Y = NSiMe3, NC(O)NH2, NH): a rational preparative route to nitrene (.mu.3-NH) clusters and the unprecedented direct exchange of an isoelectronic .mu.-NO+ ligand for a .mu.-CO ligand
Bedard, Robert L., Rae, A. David., Dahl, Lawrence F.Volume:
108
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00279a043
Date:
September, 1986
File:
PDF, 1.27 MB
english, 1986