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Formation of Cp(CO)(PR3)FeCH(OCH3)C6H5 complexes via PR3 substitution reactions, hydride addition to Cp(CO)(PR3)Fe:C(OCH3)C6H5+, and methoxide addition to Cp(CO)(PR3)Fe:CHC6H5+. Kinetic and thermodynamic diastereoselectivities. Relative reactivities of synclinal and anticlinal iron carbene isomers
Brookhart, Maurice, Buck, Robert C.Volume:
111
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00184a025
Date:
January, 1989
File:
PDF, 1.24 MB
english, 1989