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Is It Homogeneous or Heterogeneous Catalysis? Identification of Bulk Ruthenium Metal as the True Catalyst in Benzene Hydrogenations Starting with the Monometallic Precursor, Ru(II)(η 6 -C 6 Me 6 )(OAc) 2 , Plus Kinetic Characterization of the Heterogeneous Nucleation, Then Autocatalytic Surface-Growth Mechanism of Metal Film Formation
Widegren, Jason A., Bennett, Martin A., Finke, Richard G.Volume:
125
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja021436c
Date:
August, 2003
File:
PDF, 134 KB
english, 2003