Vinylplatinum carbenes and nitriles, platinoxacyclic complexes, and Heck-type coupling products formed via reaction of (.sigma.-2-propenyl)bis(triphenylphosphine)platinum(II) triflate with alkynols, nitriles, and acrylate esters. Molecular structure of [cyclic] [(PPh3)2PtCH2C(O)OCH3][OTf]

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