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Mechanism of equilibration of diastereomeric chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4-. The metal traverses between alkene enantiofaces without dissociation!
Peng, Tang Sheng, Gladysz, J. A.Volume:
114
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00037a020
Date:
May, 1992
File:
PDF, 1.37 MB
english, 1992