Apparent concurrent acetylene-vinylidenecarbene...

Apparent concurrent acetylene-vinylidenecarbene rearrangements, silyl-acetylide metathesis, and alkyne cleavage in the interaction of bis(trimethylsilyl)acetylene with (.eta.5-C5H5)Co(CO)2. Crystal and molecular structure of a novel biscarbyne complex: [.mu.3.eta.1-CSi(CH3)3][.mu.3.eta.1-C3Si(CH3)3][(.eta.5-C5H5)Co]3

Fritch, John R., Vollhardt, K. Peter C., Thompson, Michael R., Day, Victor W.
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Volume:
101
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00504a065
Date:
May, 1979
File:
PDF, 444 KB
english, 1979
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