Apparent concurrent acetylene-vinylidenecarbene rearrangements, silyl-acetylide metathesis, and alkyne cleavage in the interaction of bis(trimethylsilyl)acetylene with (.eta.5-C5H5)Co(CO)2. Crystal and molecular structure of a novel biscarbyne complex: [.mu.3.eta.1-CSi(CH3)3][.mu.3.eta.1-C3Si(CH3)3][(.eta.5-C5H5)Co]3
Fritch, John R., Vollhardt, K. Peter C., Thompson, Michael R., Day, Victor W.Volume:
101
Language:
english
Journal:
Journal of the American Chemical Society
DOI:
10.1021/ja00504a065
Date:
May, 1979
File:
PDF, 444 KB
english, 1979