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Steric control of aggregation in neutral silver(I) thiolates, [AgSR]n. Crystal and molecular structures of [AgSCH(SiMe3)2]8, a discrete molecular biscycle of weakly interacting [AgSCH(SiMe3)2]4 units, and of [AgSC(SiPhMe2)3]3 and [AgSC(SiMe3)3]4, discrete molecular monocycles containing linearly coordinated silver(I) and doubly bridging mercapto sulfur donors from novel sterically hindered thiolate ligands. A comparison with the nonmolecular structure of [Ag4{SCH2(SiMe3)}3]n1
Tang, Kaluo, Aslam, Mohammad, Block, Eric, Nicholson, Terrence, Zubieta, JonVolume:
26
Language:
english
Journal:
Inorganic Chemistry
DOI:
10.1021/ic00257a007
Date:
May, 1987
File:
PDF, 1.14 MB
english, 1987