The charge delocalised ?,?-carotene dication?preparation, structure elucidation by NMR and reactions with nucleophilesNo. 3 in the series ?Charged carotenoid species?. No. 1 = ref. 2, No.2 = ref. 3.Electronic supplementary information (ESI) available: 2D ROESY NMR spectrum of ?,?-carotene dication (5) in CDCl3 at ?20 �C. See http://www.rsc.org/suppdata/ob/b3/b307531a/

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