Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(ii) and ruthenium(iv) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{?NP(?S)(OR)2}Ph2 (R = Et, Ph)Electronic supplementary information (ESI) available: analytical and spectroscopic data. See http://www.rsc.org/suppdata/dt/b3/b305520e/

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