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Reactions of co-ordinated ligands. Part 46. Formation of [Os3(�-H)(�-CCH2CHMe2)(CO)10] and [Os3(�-H)(�-CCH?CMe2)(CO)10] by carbon?carbon ?-bond and carbon?hydrogen activation of 3,3-dimethylcyclopropene; crystal and molecular structure of [Os3(�-H)(�-CCH2CHMe2)(CO)10] and evidence for its facile rearrangement to [Os3(�-H)(�-CH?CHCHMe2)(CO)10]
Green, Michael, Orpen, A. Guy, Schaverien, Colin J.Year:
1989
Language:
english
Journal:
Journal of the Chemical Society, Dalton Transactions
DOI:
10.1039/dt9890001333
File:
PDF, 991 KB
english, 1989