Thiosemicarbazones as co-ordinating agents. Part 3. Synthesis, spectroscopic characterization, and X-ray structure of methyl pyruvate thiosemicarbazone hemihydrate, chloro(ethyl pyruvate thiosemicarbazonato)copper(II)(green form), and chloro(pyruvic acid thiosemicarbazonato)copper(II) dihydrate (blue form)

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