Effects of metal-centre orbital control on cluster character and electron distribution between borane and hydrocarbon ligands; significance of the structures of [μ-9,10-(SMe)-8,8-(PPh3)2-nido-8,7-IrSB 9H9] and [μ-9,10-(SMe)-8-(η4-C5Me5H)- nido-8,7-RhSB9H9]

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