The thermal fragmentation of 1,6-dioxa-6aλ4-thiapentalenes: formation of acylthioketenes and thioacylketenesElectronic supplementary information (ESI) available: calculated B3LYP/6-31G* IR spectra of 4b, 7b, 8b and 10. See http://www.rsc.org/suppdata/p2/b1/b104186j/

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