Correlation of the redox properties and stereochemical features of copper complexes of [18]aneN2S4(1,4,10,13-tetrathia-7,16-diazacyclooctadecane) and its N,N?-dimethyl derivative Me2[18]aneN2S4. Crystal structures of [Cu II ([18]aneN2S4)][ClO4]2�H2O, [Cu II (Me2[18]aneN2S4)][PF6]2, [Cu I2([18]aneN2S4)]BPh4, [Cu I (Me2[18]aneN2S4)]PF6 and [Cu I 2(Me2[18]aneN2S4)(NCMe)2][PF6]2

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