Reactivity of the iridium nitrosyl complex [Ir(NO)(paa)(PPh3)2][PF6]2(paa = 2-pyridinecarbaldehyde azine) with nucleophiles: insertion of NO into a methinic C?H bond; crystal structure of [Ir{(2-C5H4N)CH?N?N?C(NOH)(2-C5H4N)}{Me-(EtO)C?NH}(PPh3)2][PF6]2

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