Structure and photochemistry of new base-stabilized silylene (silanediyl) complexes R2(HMPA)Si:M(CO)n of iron, chromium, and tungsten (R = tert-BuO, tert-BuS, MesO, 1-AdaO, 2-AdaO, NeopO, TritO, Me, Cl; M = Fe, n = 4; M = Cr, W, n = 5): sila-Wittig reaction of the base-free reactive intermediate [Me2Si:Cr(CO)5] with dimethyl carbonate

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