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Structure and photochemistry of new base-stabilized silylene (silanediyl) complexes R2(HMPA)Si:M(CO)n of iron, chromium, and tungsten (R = tert-BuO, tert-BuS, MesO, 1-AdaO, 2-AdaO, NeopO, TritO, Me, Cl; M = Fe, n = 4; M = Cr, W, n = 5): sila-Wittig reaction of the base-free reactive intermediate [Me2Si:Cr(CO)5] with dimethyl carbonate
Leis, Christian, Wilkinson, Dallas L., Handwerker, Hermann, Zybill, Christian, Mueller, GerhardVolume:
11
Language:
english
Journal:
Organometallics
DOI:
10.1021/om00038a004
Date:
February, 1992
File:
PDF, 4.03 MB
english, 1992