Dinuclear coordination of a novel four-electron reduced...

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Polyhedron
2006 Vol. 25; Iss. 2
Dinuclear coordination of a novel four-electron reduced...

Polyhedron 2006 Vol. 25; Iss. 2

Dinuclear coordination of a novel four-electron reduced μ-η1,η3-allene ligand with β-agostic C–H⋯Ta interaction: Direct addition of allene to (C5Me5)2Ta2(μ-X)4 (X = Cl, Br), and molecular structure of (C5Me5)2Ta2(μ-η1,η3-C3H4)(μ-Cl)Cl3

Jui-Hsien Huang, Ting-Yu Lee, Dale C. Swenson, Louis Messerle

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Volume:

25

Year:

2006

Language:

english

Pages:

9

DOI:

10.1016/j.poly.2005.08.008

File:

PDF, 336 KB

english, 2006

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Dinuclear coordination of a novel four-electron reduced...

Dinuclear coordination of a novel four-electron reduced μ-η1,η3-allene ligand with β-agostic C–H⋯Ta interaction: Direct addition of allene to (C5Me5)2Ta2(μ-X)4 (X&#xa0;=&#xa0;Cl, Br), and molecular structure of (C5Me5)2Ta2(μ-η1,η3-C3H4)(μ-Cl)Cl3

Dinuclear coordination of a novel four-electron reduced μ-η1,η3-allene ligand with β-agostic C–H⋯Ta interaction: Direct addition of allene to (C5Me5)2Ta2(μ-X)4 (X = Cl, Br), and molecular structure of (C5Me5)2Ta2(μ-η1,η3-C3H4)(μ-Cl)Cl3