Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru2(CO)6(R-DAB) towards hetero-allenes L(L = carbodiimide, sulphine), resulting in CC bond formation. X-ray molecular structure of Ru2(CO)5 (t=BuNCHC(H)(N-t-Bu)C(N-p-Tol)N-p-Tol) and of Ru2(CO)5(i-PrNCHC(H)(N-i-Pr)C(S)C12H8)

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