Synthesis, electrochemical studies, density functional analysis and X-ray structures of trans,cis,cis-[RuCl2(N-methylimidazole)2(SbPh3)2] and trans,cis,cis-[RuCl2(4-methylpyrimidine)2(SbPh3)2]. The role of CH⋯N and CH⋯Cl interactions in pyrimidine pairings and in tuning the angular approach of imidazole residues to metals

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