From mono- to poly-nuclear heteroleptic alkaline earth-titanium complexes containing 2,2,6,6-tetramethylheptane-3,5-dionate (thd) and pyrazole (Hpz) or 3,5-dimethylpyrazole (Hpz*) ligands.: Synthesis, spectroscopic and structural characterization of [Ba(thd)2(Hpz)2]2, [Sr(thd)2(Hpz*)3], [Ba(thd)2(Hpz*)2]2 and the heterometallic {[Ti(thd)2(μ3-O)(μ-ButC(O)CH2CH2O)Sr(thd)(μ-ButCOO)]2Sr(Hpz)2}

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