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Three dinuclear copper(II) carboxylates with the paddle-wheel cage structure as intermediates in copper(II) catalyzed oxidations of carboxylic acids. X-ray crystal structures of [tetrakis(diphenyl acetato-μ-O,O′)bis(acetonitrile-N)dicopper(II)] tetrakis(acetonitrile), [tetrakis(diphenylacetato-μ-O,Ot́)bis(acetone-O)dicopper(II)] and [tetrakis(1-phenyl-1-carboxylato-μ-O,O′-cyclopentane)-bis(ethanol-O)dicopper(II)] bis (ethanol)
F.P.W. Agterberg, H.A.J. ProvóKluit, W.L. Driessen, J. Reedijk, H. Oevering, W. Buijs, N. Veldman, M.T. Lakin, A.L. SpekVolume:
267
Year:
1998
Language:
english
Pages:
10
DOI:
10.1016/s0020-1693(97)05579-5
File:
PDF, 1.68 MB
english, 1998