Synthesis and characterisation of cyclometallated orthoazobenzene complexes of Ru(II): crystal and molecular structure of [RuCl(CO)(η2-C,N-C6H4NNPh)(PPh3)2]·0.5CHCl3·0.5Et2O. Is there a similarity to the hydroxyazo/ketohydrazone tautomerisation in ortho-hydroxyazobenzenes?

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