Synthesis of novel quadruply bridged M2Se4 clusters trans/anti and trans/syn-[(η5-RC5H4)2M2(μ-Se)2(μ-SeCH2Ph)2] (M=Mo, W) via an unexpected reaction of MM triply bonded complexes [(η5-RC5H4)2M2(CO)4] with dibenzyl diselenide. Crystal structures of a pair of isomers trans/anti- and trans/syn-[(η5-EtO2CC5H4)2Mo2(μ-Se)2(μ-SeCH2Ph)2]
Li-Cheng Song, Yao-Cheng Shi, Wen-Feng Zhu, Qing-Mei Hu, Lin-Hong WengVolume:
613
Year:
2000
Language:
english
Pages:
8
DOI:
10.1016/s0022-328x(00)00502-7
File:
PDF, 173 KB
english, 2000