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Stereoselective synthesis and reactivity of cis- and trans- dimolybdenum nitrosyl derivatives with the bridging bis(dimethylsilanediyl)di(η5-cyclopentadienyl) ligand. X-ray molecular structures of cis-[Mo(CO)2(NO)2μ-(η5-C5H3)2(SiMe2)2], trans-[Mo(CO)(NO)(CNtBu)2μ-(η5-C5H3)2(SiMe2)2], cis-[Mo2(CO)3(NO)2(PMe3)μ-(η5-C5H3)2(SiMe2)2] and trans-[Mo(NO)(CNtBu)22μ-(η5-C5H3)2(SiMe2)2]
Mercedes Calvo, Mikhail V. Galakhov, Roberto Gómez-García, Pilar Gómez-Sal, Avelino Martin, Pascual Royo, Amelio Vázquez de MiguelVolume:
548
Year:
1997
Language:
english
Pages:
19
DOI:
10.1016/s0022-328x(97)00442-7
File:
PDF, 1.37 MB
english, 1997