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Reductive carbonylation route to Co(0) and Co(I) carbonyl complexes containing bridging, chelating and cleaved diphosphazanes. Structures of [Co(CO){P(OR)2(NHMe)}2{P(O)(OR)2}{P(H)(OR′)2}] (R=CH2CF3, R′=CH2CH3), [Co2(CO)2{μ-MeN{P(OR)2}2}3] (R=CH2CF3), and [Co(CO){η2-MeN{P(OR)2}2}2][CoCl3(OC4H8)] (R=Ph)
Mani Ganesan, Setharampattu S Krishnamurthy, Munirathinam NethajiVolume:
570
Year:
1998
Language:
english
Pages:
8
DOI:
10.1016/s0022-328x(98)00741-4
File:
PDF, 177 KB
english, 1998