A new family of icosahedral cages with transition metal and main group IV (14) atoms: synthesis and structural-bonding analysis of the [Ni11(SnR)2(CO)18]2- dianions (R = Bu, Me) containing nickel-centered icosahedral Ni10Sn2 cages and of their unusual [Ni(SnRCl2)4(CO)]2- precursors containing a trigonal-bipyramidal d8 nickel(II) configuration

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