Reactions of dinuclear Ni 2 complexes [Ni(RN Py S 4 )] 2 (RN Py S 4 = 2,6-bis(2-mercaptophenylthiomethyl)-4-R-pyridine) with Fe(CO) 3 (BDA) (BDA = benzylidene acetone) leading to heterodinuclear NiFe and mononuclear Fe complexes related to the active sites of [NiFe]- and [Fe]-hydrogenases