Synthesis and Stereochemical/Electrochemical Analyses of Cuboctahedral-Based Pd23(CO)x(PR3)10Clusters (x=20 with R3=Bun3, Me2Ph;x=20, 21, 22 with R3=Et3): Geometrically Analogous Pd23(PEt3)10Fragments with Variable Carbonyl Ligations and Resulting Implications

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