Cationic hydroxyallylolefin rhodium complexes [Rh(η2, 3-C7H6-3-R-2-CR1OH)(η5-Cp)]+PF6− (R, R1 = H, Alk, Cp = C5H5, C5H4Me, C5Me5) with intramolecular O-H ⋯ Rh hydrogen bonds. Formation of {[CpRh(η2, 3-C7H6-3-R-2-CR1OH)]2-F2POO}+PF6− dimers as a result of partial hydrolysis of the PF6− anion

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