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Copper(I) 1,1-dithiolate cluster transformations. Synthesis of [Bu4N]6[Cu6(S,i-MNT)6], i-MNT=[S2CC(CN)2]−, from [Bu4N]4[Cu8(i-MNT)6] with sulfur. Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral [Bu4N]4[Cu4(i-MNT)4] which oxidizes in solution to give the homocubane [Bu4N]4[Cu8(i-MNT)6] and [Bu4N]2[Cu(i-MNT)2]
C.W. Liu, Richard J. Staples, John P. FacklerVolume:
174
Year:
1998
Language:
english
Pages:
31
DOI:
10.1016/s0010-8545(98)00049-6
File:
PDF, 531 KB
english, 1998