Volume 67; Issue 7

Journal of Organic Chemistry

Volume 67; Issue 7

1

Chiral Tricyclic Iminolactone Derived from (1R)-(+)-Camphor as a Glycine Equivalent for the Asymmetric Synthesis of α-Amino Acids

Xu, Peng-Fei, Chen, Yuan-Shek, Lin, Shu-I, Lu, Ta-Jung

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 159 KB

english, 2002

2

Biosynthetic Precursors of the Lipase Inhibitor Lipstatin

Schuhr, Christoph A., Eisenreich, Wolfgang, Goese, Markus, Stohler, Peter, Weber, Wolfgang, Kupfer, Ernst, Bacher, Adelbert

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 78 KB

english, 2002

3

Preparation of 2,6-Dimethyl-4-arylpyridine- 3,5-dicarbonitrile: A Paired Electrosynthesis†

Batanero, Belén, Barba, Fructuoso, Martín, Avelino

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 44 KB

english, 2002

4

Ipso Substitution as a Route to Benzo[c]quinolizines and 4-Hydroxycoumarins

Liu, Yannan, Kurth, Mark J.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 65 KB

english, 2002

5

Nucleophilic Catalysis with 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) for the Esterification of Carboxylic Acids with Dimethyl Carbonate

Shieh, Wen-Chung, Dell, Steven, Repič, Oljan

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 60 KB

english, 2002

6

A General Method for the Preparation of 4- and 6-Azaindoles

Zhang, Zhongxing, Yang, Zhong, Meanwell, Nicholas A., Kadow, John F., Wang, Tao

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 41 KB

english, 2002

7

Synthesis of Some Unsymmetrical Bridged Terpyridines

Kelly, T. Ross, Lebedev, Rimma L.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 136 KB

english, 2002

8

Substituent Effects on the Thermal Cis-to-Trans Isomerization of 1,3-Diphenyltriazenes in Aqueous Solution

Chen, Nan, Barra, Mónica, Lee, Ivan, Chahal, Navjot

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 172 KB

english, 2002

9

Unique Charge-Separated Pyridinium-Barbituric Acid Zwitterions

Jursic, Branko S., Neumann, Donna M., Moore, Zakhia, Stevens, Edwin D.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 52 KB

english, 2002

10

Diastereoselective Reactions in Glycine Templates Containing an ent -Ardeemin Fragment

Martín-Santamaría, Sonsoles, Corzo-Suárez, Raúl, Avendaño, Carmen, Espada, Modesta, Gago, Federico, García-Granda, Santiago, Rzepa, Henry S.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 127 KB

english, 2002

11

Cephalocyclidin A, a Novel Pentacyclic Alkaloid from Cephalotaxus h arringtonia var . n ana

Kobayashi, Jun'ichi, Yoshinaga, Miwa, Yoshida, Naotoshi, Shiro, Motoo, Morita, Hiroshi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 92 KB

english, 2002

12

Photochemistry of Arylidene- β -ionones: A Highly Efficient Route to Novel Tricyclic Ketones through Intramolecular, Exoselective Photochemical (4 + 2) Cycloadditions, Occurring Only in an Aqueous−Organic Solvent

Ishar, Mohan Paul S., Singh, Rajinder, Kumar, Kamal, Singh, Gurmit, Velmurugan, D., Pandi, A. Subbiah, Raj, S. S. Sundra, Fun, H. K.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 99 KB

english, 2002

13

Aromatization of 1,6,7,7a-Tetrahydro-2 H -indol-2-ones by a Novel Process. Preparation of Key-Intermediate Methyl 1-Benzyl-5-methoxy-1 H -indole-3-acetate and the Syntheses of Serotonin, Melatonin, and Bufotenin

Revial, Gilbert, Jabin, Ivan, Lim, Sethy, Pfau, Michel

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 76 KB

english, 2002

14

A Novel Crown Ether Generation Containing Different Heteroaromatic Cations: Synthesis, Characterization, Solid-Phase 13 C NMR, X-ray Crystal Structure, and Selective Amino Acid Recognition

Moghimi, Abolghasem, Rastegar, Majid Faal, Ghandi, Mehdi, Taghizadeh, Masoud, Yari, Abdollah, Shamsipur, Mojtaba, Yap, Glenn P. A., Rahbarnoohi, Hamid

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 147 KB

english, 2002

15

First Total Synthesis of Artepillin C Established by o , o ‘ -Diprenylation of p -Halophenols in Water

Uto, Yoshihiro, Hirata, Akihiko, Fujita, Tomoya, Takubo, Syunsuke, Nagasawa, Hideko, Hori, Hitoshi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 77 KB

english, 2002

16

Rearrangement of 2-Aryl-3,3-dichloroazetidines: Intermediacy of 2-Azetines

Dejaegher, Yves, Mangelinckx, Sven, De Kimpe, Norbert

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 101 KB

english, 2002

17

Enantioselective Allyltitanations and Metathesis Reactions. Application to the Synthesis of Piperidine Alkaloids (+)-Sedamine and (−)-Prosophylline

Cossy, Janine, Willis, Catherine, Bellosta, Véronique, BouzBouz, Samir

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 149 KB

english, 2002

18

Asymmetric N1 Unit Transfer to Olefins with a Chiral Nitridomanganese Complex: Novel Stereoselective Pathways to Aziridines or Oxazolines

Nishimura, Masaaki, Minakata, Satoshi, Takahashi, Toru, Oderaotoshi, Yoji, Komatsu, Mitsuo

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 141 KB

english, 2002

19

Highly Diastereoselective Aziridination of Imines with Trimethylsilyldiazomethane. Subsequent Silyl Substitution with Electrophiles, Ring Opening, and Metalation of C -SilylaziridinesA Cornucopia of Highly Selective Transformations

Aggarwal, Varinder K., Alonso, Emma, Ferrara, Marco, Spey, Sharon E.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 144 KB

english, 2002

20

Investigation of Synthetic Hosts That Model Cation-π Sites Found at Protein Binding Domains

Dvornikovs, Vadims, Smithrud, David B.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 191 KB

english, 2002

21

A Highly Enantioselective Hetero-Diels−Alder Reaction of Aldehydes with Danishefsky's Diene Catalyzed by Chiral Titanium(IV) 5,5‘,6,6‘,7,7‘,8,8‘-Octahydro-1,1‘-bi-2-naphthol Complexes

Wang, Bin, Feng, Xiaoming, Huang, Yaozong, Liu, Hui, Cui, Xin, Jiang, Yaozhong

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 121 KB

english, 2002

22

Cycloaddition Reaction of 2-Azadienes Derived from β-Amino Acids with Electron-Rich and Electron-Deficient Alkenes and Carbonyl Compounds. Synthesis of Pyridine and 1,3-Oxazine Derivatives

Palacios, Francisco, Herrán, Esther, Rubiales, Gloria, Ezpeleta, Jose María

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 76 KB

english, 2002

23

Direct Synthesis of 5-Substituted Naphthoquinones

Kraus, George A., Kim, Junwon

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 39 KB

english, 2002

24

Investigation of the Binding of Epimer A of the Covalent Hydrate of 6,7-Bis(trifluoromethyl)-8- d -ribityllumazine to a Recombinant F22W Bacillus subtilis Lumazine Synthase Mutant by 15 N{ 19 F} REDOR NMR

Mehta, Anil K., Studelska, Daniel R., Fischer, Markus, Giessauf, Andreas, Kemter, Kristina, Bacher, Adelbert, Cushman, Mark, Schaefer, Jacob

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 83 KB

english, 2002

25

Glaser-Mediated Synthesis and Photophysical Characterization of Diphenylbutadiyne-Linked Porphyrin Dyads

Youngblood, W. Justin, Gryko, Daniel T., Lammi, Robin K., Bocian, David F., Holten, Dewey, Lindsey, Jonathan S.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 96 KB

english, 2002

26

A Convenient Preparation of Functionalized 1,8-Dioxygenated Naphthalenes from 6-Alkoxybenzocyclobutenones

Bungard, Christopher J., Morris, Jonathan C.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 53 KB

english, 2002

27

Decarbonylative Radical Cyclization of α-Amino Selenoesters upon Electrophilic Alkenes. A General Method for the 6-Azabicyclo[3.2.1]octane Synthesis

Quirante, Josefina, Vila, Xavier, Escolano, Carmen, Bonjoch, Josep

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 83 KB

english, 2002

28

Structure/Activity Study of Tris(2-aminoethyl)amine-Derived Translocases for Phosphatidylcholine

Boon, J. Middleton, Lambert, Timothy N., Smith, Bradley D., Beatty, Alicia M., Ugrinova, Vesela, Brown, Seth N.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 176 KB

english, 2002

29

Pyrene-Armed Calix[4]azacrowns as New Fluorescent Ionophores: “Molecular Taekowndo” Process via Fluorescence Change

Kim, Jong Seung, Shon, Ok Jae, Rim, Jeong Ah, Kim, Sook Kyung, Yoon, Juyoung

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 159 KB

english, 2002

30

Recent Reviews. 64

Cornel, Veronica M.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 32 KB

english, 2002

31

Palladium-Catalyzed Carbonylative Annulation of o- Alkynylphenols: Syntheses of 2-Substituted-3-aroyl-benzo[ b ]furans

Hu, Youhong, Zhang, Yan, Yang, Zhen, Fathi, Reza

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 72 KB

english, 2002

32

Synthesis of Syn and Anti Isomers of trans -Cyclopropyl Arginine

Fishlock, Dan, Guillemette, J. Guy, Lajoie, Gilles A.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 44 KB

english, 2002

33

Isomerization of Substituted Biphenyls by Superacid. A Remarkable Confluence of Experiment and Theory

Sherman, S. Christopher, Iretskii, Alexei V., White, Mark G., Gumienny, Charles, Tolbert, Laren M., Schiraldi, David A.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 169 KB

english, 2002

34

Addition of Bromine Chloride and Iodine Monochloride to Carbonyl-Conjugated, Acetylenic Ketones: Synthesis and Mechanisms †

Heasley, Victor L., Buczala, Deanna M., Chappell, Alfred E., Hill, David J., Whisenand, Josh M., Shellhamer, Dale F.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 67 KB

english, 2002

35

Total Synthesis of Gibbilimbols A−D

Vyvyan, James R., Holst, Christian L., Johnson, Allison J., Schwenk, Cheryl M.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 35 KB

english, 2002

36

Novel [2 + 2] Photocycloaddition-Induced Rearrangement of Bichromophoric Naphthalene-Tethered Resorcinol Ethers

Hoffmann, Norbert, Pete, Jean-Pierre, Inoue, Yoshihisa, Mori, Tadashi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 109 KB

english, 2002

37

Tuning of Regioselectivity in the Coupling Reaction Involving Allenic/Propargylic Palladium Species

Ma, Shengming, Zhang, Aibin

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 126 KB

english, 2002

38

In Situ Formation of Allyl Ketones via Hiyama−Nozaki Reactions Followed by a Chromium-Mediated Oppenauer Oxidation

Schrekker, Henri S., de Bolster, Martin W. G., Orru, Romano V. A., Wessjohann, Ludger A.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 92 KB

english, 2002

39

Novel Acid-Catalyzed Rearrangement of Tetrahydro-1,2,3,4-tetrazines: Unexpected Formation of Glycosazones

Avalos, Martín, Babiano, Reyes, Cintas, Pedro, Clemente, Fernando R., Gordillo, Ruth, Hursthouse, Michael B., Jiménez, José L., Light, Mark E., Palacios, Juan C.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 74 KB

english, 2002

40

Novel Chiral Biferrocene Ligands for Palladium-Catalyzed Allylic Substitution Reactions

Xiao, Li, Weissensteiner, Walter, Mereiter, Kurt, Widhalm, Michael

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 166 KB

english, 2002

41

Titanium Isopropoxide as Efficient Catalyst for the Aza-Baylis−Hillman Reaction. Selective Formation of α-Methylene-β-amino Acid Derivatives

Balan, Daniela, Adolfsson, Hans

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 85 KB

english, 2002

42

Synthesis of 1,2,7,7a-Tetrahydro-1a H -cyclopropa[ b ]quinoline-1a-carboxylic Acid Derivatives, Doubly Constrained ACC Derivatives, by a Remarkable Cyclopropanation Process

Szakonyi, Zsolt, Fülöp, Ferenc, Tourwé, Dirk, De Kimpe, Norbert

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 83 KB

english, 2002

43

Diastereoselective Nucleophilic Substitution Reactions of Oxasilacyclopentane Acetals: Application of the “Inside Attack” Model for Reactions of Five-Membered Ring Oxocarbenium Ions

Bear, Teresa J., Shaw, Jared T., Woerpel, K. A.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 137 KB

english, 2002

44

Regiocontrolled Synthesis of Enantiopure 3,3‘-Thiosubstituted Biphenyls

Capozzi, Giuseppe, Delogu, Giovanna, Fabbri, Davide, Marini, Manuela, Menichetti, Stefano, Nativi, Cristina

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 134 KB

english, 2002

45

Synthesis of New Transglycosidically Tethered 5‘-Nucleotides Constrained to a Highly Biologically Relevant Profile

Groziak, Michael P., Thomas, David W.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 120 KB

english, 2002

46

Daphnicyclidins J and K, Unique Polycyclic Alkaloids from Daphniphyllum h umile

Morita, Hiroshi, Yoshida, Naotoshi, Kobayashi, Jun'ichi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 112 KB

english, 2002

47

Spectral Properties and Absolute Rate Constants for β-Scission of Ring-Substituted Cumyloxyl Radicals. A Laser Flash Photolysis Study

Baciocchi, Enrico, Bietti, Massimo, Salamone, Michela, Steenken, Steen

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 65 KB

english, 2002

48

Studies on Novel Peptidomimetics Having Bi-directional Dispositions of Hydroxylated d -Pro-Gly Motifs Anchored on a C 2 -Symmetric Iminosugar-Based Foundation

Chakraborty, T. K., Srinivasu, P., Kumar, S. Kiran, Kunwar, A. C.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 132 KB

english, 2002

49

Kinetics of Hydrolysis of 8-(Arylamino)-2‘-deoxyguanosines

Novak, Michael, Ruenz, Megan, Kazerani, Shahrokh, Toth, Krisztina, Nguyen, Thach-Mien, Heinrich, Brian

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 85 KB

english, 2002

50

Transition-State Variation in the Nucleophilic Substitution Reactions of Aryl Bis(4-methoxyphenyl) Phosphates with Pyridines in Acetonitrile

Lee, Hai Whang, Guha, Arun Kanti, Kim, Chang Kon, Lee, Ikchoon

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 117 KB

english, 2002

51

Ab Initio Study of 1,4-Pentadienyl Electrocyclic Reactions

Martinez, C., Cooksy, A. L.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 140 KB

english, 2002

52

Synthesis of 2-Alkylidenecyclopentanones via Palladium-Catalyzed Carbopalladation/Ring Expansion of 1-(1-Alkynyl)cyclobutanols †

Larock, Richard C., Reddy, Ch. Kishan

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 79 KB

english, 2002

53

Inversion vs Retention of Configuration in Gas-Phase Ammonium Ion/Alcohol Reactions.

Sauers, Ronald R.

Journal:

Journal of Organic Chemistry

Year:

2002

File:

PDF, 11 KB

2002

54

Intramolecularly Competitive Ireland-Claisen Rearrangements: Scope and Potential Applications to Natural Product Synthesis

Hong, Sang-phyo, Lindsay, Harriet A., Yaramasu, Tripura, Zhang, Xiaowei, McIntosh, Matthias C.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 189 KB

english, 2002

55

Stereospecificity of an Enzymatic Monoene 1,4-Dehydrogenation Reaction: Conversion of ( Z )-11-Tetradecenoic Acid into ( E , E )-10,12-Tetradecadienoic Acid

Rodríguez, Sergio, Clapés, Pere, Camps, Francisco, Fabriàs, Gemma

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 71 KB

english, 2002

56

Dications of Fluorenylidenes. Relationship between Electrochemical Oxidation Potentials and Antiaromaticity in Diphenyl-Substituted Fluorenyl Cations

Mills, Nancy S., Benish, Michele A., Ybarra, Christie

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 122 KB

english, 2002

57

Experimental and Theoretical Insights Regarding the Cycloaddition Reaction of Carbohydrate-Based 1,2-Diaza-1,3-butadienes and Acrylonitrile. A Model Case for the Behavior of Chiral Azoalkenes and Unsymmetric Olefins †

Avalos, Martín, Babiano, Reyes, Cintas, Pedro, Clemente, Fernando R., Gordillo, Ruth, Jiménez, José L., Palacios, Juan C.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 165 KB

english, 2002

58

Hydroxy-Directed Diastereoselective Installation of a Methyl Group on Indalone Models and Spiroketal Potential Precursors for the Bafilomycin A 1 C15−C25 Subunit

Poupon, Jean-Christophe, Lopez, Roman, Prunet, Joëlle, Férézou, Jean-Pierre

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 100 KB

english, 2002

59

3,3-Disubstituted Allyl Alcohols from Palladium-Catalyzed Coupling of Hydroaluminated Propargyl Alcohols with Aryl Iodides

Havránek, Miroslav, Dvořák, Dalimil

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 85 KB

english, 2002

60

Effect of Multivalency on the Performance of Enantioselective Separation Media for Chiral HPLC Prepared by Linking Multiple Selectors to a Porous Polymer Support via Aliphatic Dendrons

Ling, Frank H., Lu, Victor, Svec, Frantisek, Fréchet, Jean M. J.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 120 KB

english, 2002

61

Synthesis and Photochromism of Spirobenzopyrans and Spirobenzothiapyran Derivatives Bearing Monoazathiacrown Ethers and Noncyclic Analogues in the Presence of Metal Ions

Tanaka, Mutsuo, Ikeda, Tomokazu, Xu, Qiang, Ando, Hisanori, Shibutani, Yasuhiko, Nakamura, Makoto, Sakamoto, Hidefumi, Yajima, Setsuko, Kimura, Keiichi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 93 KB

english, 2002

62

Regioselective Lithiation and Functionalization of 3-(Benzyloxy)isothiazole: Application to the Synthesis of Thioibotenic Acid

Bunch, Lennart, Krogsgaard-Larsen, Povl, Madsen, Ulf

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 49 KB

english, 2002

63

5-[4-(1-Hydroxyethyl)phenyl]-10,15,20-triphenylporphyrin as a Probe of the Transition-State Conformation in Hydrolase-Catalyzed Enantioselective Transesterifications

Ema, Tadashi, Jittani, Masahito, Furuie, Kenji, Utaka, Masanori, Sakai, Takashi

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 231 KB

english, 2002

64

Allylic Phosphates and Allylic Phosphinates as Electrophiles in Efficient Silylcupration Reactions of Acetylenes

Liepins, Vilnis, Karlström, A. Sofia E., Bäckvall, Jan-E.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 95 KB

english, 2002

65

Imidazopyridinium and Pyridopyrimidium Bromides: Synthesis and Hydrolysis

Huang, Kevin S., Haddadin, Makhluf J., Kurth, Mark J.

Journal:

Journal of Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 55 KB

english, 2002