Volume 101; Issue 21

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Journal of the American Chemical Society
Volume 101; Issue 21

Journal of the American Chemical Society

Volume 101; Issue 21

1

Fast radical reactions in a mass spectrometer ion source: radical addition to 7,7,8,8-tetracyanoquinodimethane

McEwen, C. N., Rudat, M. A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 340 KB

english, 1979

2

Molecular transformations in the solid state. Crystallographic resolution of the spin isomers of tris(2-picolylamine)iron(II) dichloride and the structural relationship between the methanol and ethanol solvates

Katz, Bradley A., Strouse, Charles E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 999 KB

english, 1979

3

Use of tetraphenylborate as a phase transfer agent for acid catalysis

Snipes, Stephen, Herriott, Arthur W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 150 KB

english, 1979

4

Solid catalyst treated with anion. 2. Reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion. Solid superacid catalyst

Hino, Makoto, Kobayashi, Sakari, Arata, Kazushi

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 440 KB

english, 1979

5

Water solvent exchange rates of primary amides. Acid-catalyzed NMR saturation transfer as an indicator of rotation and structure of the protonated form

Redfield, A. G., Waelder, S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.44 MB

english, 1979

6

The penems, a new class of .beta.-lactam antibiotics. 4. Syntheses of racemic and enantiomeric penem carboxylic acids

Pfaendler, H. R., Gosteli, J., Woodward, R. B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 643 KB

english, 1979

7

Hyperconjugation and homohyperconjugation in the 1-adamantyl cation. Qualitative models for .gamma.-deuterium isotope effects

Sunko, Dionis E., Hirsl-Starcevic, S., Pollack, Steven K., Hehre, Warren J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 956 KB

english, 1979

8

New conjunctive reagents. 2-Acetoxymethyl-3-allyltrimethylsilane for methylenecyclopentane annulations catalyzed by palladium(0)

Trost, Barry M., Chan, Dominic M. T.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 374 KB

english, 1979

9

P-450 type oxygen activation by porphyrin-manganese complex

Tabushi, Iwao, Koga, Noboru

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 401 KB

english, 1979

10

Nickel-boron "hybrid" clusters. Synthesis of polyhedral nickelaboranes and nickelacarboranes from small borane and carborane anions. Crystal structure of (.eta.5-C5H5)4Ni4B4H4

Bowser, James R., Bonny, Alan, Pipal, J. Robert, Grimes, Russell N.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.04 MB

english, 1979

11

Mechanism of oxidative addition. Reaction of nickel(0) complexes with aromatic halides

Tsou, T. T., Kochi, J. K.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.60 MB

english, 1979

12

Dioxygen complexes of rhodium porphyrins

Wayland, Bradford B., Newman, Alan R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 202 KB

english, 1979

13

A calorimetric titration study of the reaction of several organic ammonium cations with 18-crown-6 in methanol

Izatt, R. M., Lamb, J. D., Izatt, N. E., Rossiter, B. E., Christensen, J. J., Haymore, B. L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 448 KB

english, 1979

14

Mechanism of ligand substitution on high-spin iron(III) by hydroxamic acid chelators. Thermodynamic and kinetic studies on the formation and dissociation of a series of monohydroxamatoiron(III) complexes

Monzyk, Bruce, Crumbliss, Alvin L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.39 MB

english, 1979

15

Properties and reactions of manganese methylene complexes in the gas phase. The importance of strong metal-carbene bonds for effective olefin metathesis catalysts

Stevens, Amy E., Beauchamp, J. L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 286 KB

english, 1979

16

Methylides from trimethylsilylmethylsulfonium, -ammonium, -immonium, and -phosphonium salts

Vedejs, E., Martinez, G. R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 401 KB

english, 1979

17

Generation of specific isomeric carbanions in the gas phase

DePuy, C. H., Bierbaum, Veronica M., Flippin, L. A., Grabowski, Joseph J., King, Gary K., Schmitt, Robert J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 152 KB

english, 1979

18

Energy deposition in polyatomic ions upon high energy collision by angle-resolved mass spectrometry

Laramee, J. A., Hemberger, P. H., Cooks, R. G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 364 KB

english, 1979

19

Studies in nuclear magnetic resonance spectroscopy. 16. Nonsymmetry of the hydrogen bond in 1-phenylamino-7-phenylimino-1,3,5-cycloheptatriene

Jackman, L. M., Trewella, J. C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 272 KB

english, 1979

20

Synthesis of the nontryptamine moiety of the Aspidosperma-type indole alkaloids via cleavage of a cyclic .alpha.-diketone monothioketal. An efficient synthesis of (.+-.)-quebrachamine and a formal synthesis of (.+-.)-tabersonine

Takano, Seiichi, Hatakeyama, Susumi, Ogasawara, Kunio

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 950 KB

english, 1979

21

Strong metal-to-metal quadruple bonds in a series of five isostructural compounds as indicated by photoelectron spectroscopy

Bursten, Bruce E., Cotton, F. Albert, Cowley, Alan H., Hanson, Brian E., Lattman, Michael, Stanley, George G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 703 KB

english, 1979

22

Organic photochemistry with 6.7-eV photons: irradiation of molecular oxygen in hydrocarbon solution

Srinivasan, R., White, Lloyd S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 508 KB

english, 1979

23

Model compounds for the interaction of silver(I) with polyuridine. Crystal structure of a 1:1 silver complex with 1-methylthymine

Guay, France, Beauchamp, Andre L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 488 KB

english, 1979

24

Three-electron oxidations. 16. Chromic acid oxidation of mandelic acid

Ip, Dominic, Rocek, Jan

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 992 KB

english, 1979

25

Concurrent general acid and general base catalysis in the hydrolysis of an imidate ester. 3. Ethyl N-p-nitrophenylformimidate

Lee, Yin-Nan, Schmir, Gaston L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 744 KB

english, 1979

26

Cyclic peroxides. 88. Reaction of 7-substituted cycloheptatrienes with singlet oxygen and 4-phenyl-1,2,4-triazoline-3,5-dione

Adam, Waldemar, Balci, Metin, Pietrzak, Barbara

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 705 KB

english, 1979

27

Photochemical oxidation and rearrangement of dibenzobarrelene and dehydrojanusene

Bartlett, Paul D., Kimura, Michio, Nakayama, Jyuzo, Watson, William H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 789 KB

english, 1979

28

An ab initio molecular orbital study of 2- and 4-monosubstituted pyridines

Del Bene, Janet E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 725 KB

english, 1979

29

Formation of hydridocyclotriphosphazenes via the reactions of organocopper reagents with halocyclotriphosphazenes. Reaction mechanism

Allcock, Harry R., Harris, Paul J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 960 KB

english, 1979

30

Gas-phase reactions of carbanions with triplet and singlet molecular oxygen

Schmitt, Robert J., Bierbaum, Veronica M., DePuy, C. H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 391 KB

english, 1979

31

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 635 KB

english, 1979

32

Photochemical electron transfer in monolayer assemblies. 1. Spectroscopic study of radicals produced in chlorophyll a/acceptor systems

Janzen, A. Frederick, Bolton, James R., Stillman, Martin J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 591 KB

english, 1979

33

Intramolecular electron transfer from pentacyanoferrate(II) to pentaamminecobalt(III) mediated by various 4,4'-bipyridines

Jwo, Jing-Jer, Gaus, P. L., Haim, Albert

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.18 MB

english, 1979

34

Reactions of ketones and related compounds with solid supported phosphoric acid catalyst. 5. Mechanisms of acid-catalyzed aliphatic ketone rearrangements and relationships between ketone structure and oxygen function rearrangement.

Fry, Arthur, Oka, Mitsuo

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.22 MB

english, 1979

35

Chemical synthesis of a proposed enzyme-generated "reactive intermediate analog" derived from thiamin diphosphate. Self-activation of pyruvate dehydrogenase by conversion of the analog to its components

Kluger, Ronald, Pike, David C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 507 KB

english, 1979

36

Elucidation of chemical exchange networks by two-dimensional NMR spectroscopy: the heptamethylbenzenonium ion

Meier, B. H., Ernst, R. R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 279 KB

english, 1979

37

The penems, a new class of .beta.-lactam antibiotics. 2. Total synthesis of racemic 6-unsubstituted representatives

Lang, M., Prasad, K., Holick, W., Gosteli, J., Ernest, I., Woodward, R. B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 822 KB

english, 1979

38

Triplet state photophysical properties and intersystem crossing quantum efficiencies of homologs of retinals in various solvents

Das, Paritosh K., Becker, Ralph S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 769 KB

english, 1979

39

Carbon-carbon bond homolysis in hexakis(trifluoromethylmercapto)ethane at room temperature. Thermodynamic, kinetic, and electron spin resonance results

Haas, A., Schlosser, K., Steenken, S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 392 KB

english, 1979

40

Photochemical electron transfer in monolayer assemblies. 2. Photoelectric behavior in chlorophyll a/acceptor systems

Janzen, A. Frederick, Bolton, James R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 829 KB

english, 1979

41

Reversible loss of metal ions from the zinc binding site of copper-zinc superoxide dismutase. The low pH transition

Pantoliano, Michael W., McDonnell, Peter J., Valentine, Joan S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 376 KB

english, 1979

42

Photochemical decomposition of trimethylsilyl diazoacetates in alcohols

Ando, Wataru, Sekiguchi, Akira, Hagiwara, Tsuneo, Migita, Toshihiko, Chowdhry, Vinay, Westheimer, F. H., Kammula, Seetha L., Green, Marilyn, Jones, Maitland

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 673 KB

english, 1979

43

Electronic structure of the lowest 1A1 and 3B1 states of cyclopropenylidene

Shepard, Ron, Banerjee, Ajit, Simons, Jack

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 676 KB

english, 1979

44

Synthesis and properties of .pi.-bonded olefin and acetylene complexes of ruthenium(II). Crystal and molecular structure of the pentaammineruthenium(II) fumaric acid complex, [(NH3)5Ru(C4H4O4)]S2O6.2H2O

Lehmann, H., Schenk, K. J., Chapuis, G., Ludi, A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 685 KB

english, 1979

45

Facile hydroxymethylation of an acyloxymethyl ligand with synthesis gas or hydrogen. A model for catalytic reactions yielding methanol and ethylene glycol

Dombek, B. Duane

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 413 KB

english, 1979

46

Intramolecular rearrangement of carbonyl ligands in the octahedral complex pentacarbonyl(trimethyl phosphite) tungsten by a nondissociative process: an example of the utility of the oxygen-18 isotope shift on the carbon-13 NMR of the carbonyl ligand

Darensbourg, Donald J., Baldwin, Brenda J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 385 KB

english, 1979

47

2-Acetoxymethyl-3-allyltrimethylsilane and palladium(0): a source of trimethylenemethane-palladium complex?

Trost, Barry M., Chan, Dominic M. T.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 253 KB

english, 1979

48

Dihydrogen reduction of isocyanides promoted by permethylzirconocene dihydride. A modeling study of carbon monoxide reduction

Wolczanski, Peter T., Bercaw, John E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 383 KB

english, 1979

49

Photoreaction of valence-bond isomers of hexakis(trifluoromethyl)oxepin. Synthesis of a stable oxetene derivative

Kobayashi, Yoshiro, Hanzawa, Yuji, Miyashita, Wakako, Kashiwagi, Takashi, Nakano, Takaharu, Kumadaki, Itsumaro

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 252 KB

english, 1979

50

Chemically derivatized n-type semiconducting gallium arsenide photoelectrodes. Thermodynamically uphill oxidation of surface-attached ferrocene centers

Bolts, Jeffrey M., Wrighton, Mark S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 725 KB

english, 1979

51

Arylcyclopropane photochemistry. Electron-transfer-mediated photochemical addition of methanol to arylcyclopropanes

Rao, V. Ramachandra, Hixson, Stephen S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 256 KB

english, 1979

52

Conformational effects upon the charge-transfer transitions of the hexamethylbenzene-tetracyanoethylene crystalline complex

Eckhardt, C. J., Hood, R. J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 646 KB

english, 1979

53

Acyclic mechanism in the cleavage of benzils with alkaline hydrogen peroxide

Sawaki, Yasuhiko, Foote, Christopher S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 557 KB

english, 1979

54

Enhancement of decomposition quantum yields of reluctant azoalkanes

Engel, Paul S., Nalepa, Christopher J., Leckonby, Roy A., Chae, Woo-Ki

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 399 KB

english, 1979

55

Masthead

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 117 KB

english, 1979

56

Reactions of benzaldehyde with trialkylsilyl metal carbonyl complexes

Johnson, Dennis Lee, Gladysz, J. A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 383 KB

english, 1979

57

Lactone annulation of .beta.-keto esters with .beta.-vinylbutenolide and the total synthesis of racemic frullanolide

Kido, Fusao, Tsutsumi, Kentaro, Maruta, Riichiro, Yoshikoshi, Akira

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 672 KB

english, 1979

58

X-ray crystallographic results on tantallacyclopentane complexes derived from ethylene and 1,6-heptadiene: Ta(.eta.5-C5Me5)(C4H8)Cl2 and Ta(.eta.5-C5Me5)(C7H12)Cl2

Churchill, Melvyn Rowen, Youngs, Wiley J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 243 KB

english, 1979

59

Synthesis, crystal structure, and properties of the hexa(.mu.-benzenethiolato)tetra(benzenethiolatocobaltate(II)) dianion, the prototype cobalt(II)-thiolate molecular cluster

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.17 MB

english, 1979

60

Studies on transfer ribonucleic acids and related compounds. 29. Synthesis of a decaribonucleotide of Escherichia coli tRNAfMet (bases 11-20) using a new phosphorylating reagent

Ohtsuka, Eiko, Tanaka, Toshiki, Ikehara, Morio

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 641 KB

english, 1979

61

Resolutions using metal complexes. Synthesis, separation into diastereoisomers, and resolution of o-phenylenebis(methylphenylphosphine) using palladium complexes containing optically active ortho-metalated dimethyl(.alpha.-methylbenzyl)amines

Roberts, Nicholas K., Wild, Stanley Bruce

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 950 KB

english, 1979

62

Chemistry of exciplexes. 8. The role of conservation of orbital symmetry in cycloadditions of olefins to aromatic hydrocarbons

Yang, Nien-chu C., Masnovi, John, Chiang, Wei-long

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 264 KB

english, 1979

63

Unusual organic photochemistry effected by cyano and methoxy substitution. Exploratory and mechanistic organic photochemistry

Zimmerman, Howard E., Armesto, Diego, Amezua, Mercedes G., Gannett, Thomas P., Johnson, Richard P.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 2.11 MB

english, 1979

64

Photodissociation spectroscopy of alkane radical cations

Benz, Robert C., Dunbar, Robert C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 472 KB

english, 1979

65

Reactions of vinylcyclopropane induced by multiphoton absorption of infrared radiation

Farneth, William E., Thomsen, Marcus W., Berg, Mark A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 386 KB

english, 1979

66

Photochemistry of cis-1-phenylcyclohexene. Proof of involvement of trans isomer in reaction processes

Dauben, W. G., Van Riel, H. C. H. A., Robbins, J. D., Wagner, G. J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 905 KB

english, 1979

67

Helium (He I) photoelectron spectrum of benzocyclobutadiene

Koenig, T., Imre, Daniel, Hoobler, James A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 228 KB

english, 1979

68

Bimetal vapor-polymer chemistry at close to room temperature. A new synthetic pathway to mononuclear and cluster bimetallic polymers

Francis, Colin G., Huber, Helmut, Ozin, Geoffrey A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 497 KB

english, 1979

69

Onium ions. 21. Cyclopropylhalonium ions

Olah, George A., Prakash, G. K. Surya, Bruce, Mark R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 376 KB

english, 1979

70

[1:2,9:10]Bismethano[2.2]paracyclophane

Truesdale, E. A., Hutton, R. S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 216 KB

english, 1979

71

A total synthesis of reserpine

Pearlman, Bruce A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 673 KB

english, 1979

72

Cyclopropanation of olefins with a stable, iron-containing methylene transfer reagent

Brandt, Steven, Helquist, Paul

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 355 KB

english, 1979

73

The penems, a new class of .beta.-lactam antibiotics. 3. Synthesis of optically active 2-methyl-(5R)-penem-3-carboxylic acid

Ernest, I., Gosteli, J., Woodward, R. B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 683 KB

english, 1979

74

A method for effecting the equivalent of a de Mayo reaction with formyl acetic ester

Pearlman, Bruce A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 923 KB

english, 1979

75

Substituent effects in cluster species. 2. Photoelectron spectra of 2- and 2,4-substituted 1,6-dicarba-closo-hexaborane(6)

Beltram, G. A., Fehlner, T. P.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 971 KB

english, 1979

76

One-electron oxidation of vinylidene-carbene complexes of iron porphyrins. Isolation of complexes spectrally analogous to catalase and horseradish peroxidase compounds I

Mansuy, D., Lange, M., Chottard, J. C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 412 KB

english, 1979