Volume 101; Issue 3

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Journal of the American Chemical Society
Volume 101; Issue 3

Journal of the American Chemical Society

Volume 101; Issue 3

1

Enhancement of nuclear magnetic resonance signals by polarization transfer

Morris, Gareth A., Freeman, Ray

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 402 KB

english, 1979

2

Effect of ligand asymmetry on the structure and reactivity of CpMLL'(allyl) (Cp = cyclopentadienyl, M = metal, L = ligand) and -(ethylene) complexes

Schilling, Birgitte E. R., Hoffmann, Roald, Faller, J. W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 840 KB

english, 1979

3

Stereospecific synthesis of (.+-.)-trisporol B, a prohormone of Blakeslea trispora, and a facile synthesis of (.+-.)-trisporic acids

Prisbylla, Michael P., Takabe, Kunihiko, White, James D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 281 KB

english, 1979

4

Stabilization of D3h pentacoordinate carbonium ions. Linear three-center-two-electron bonds. Implications for aliphatic electrophilic substitution reactions

Jemmis, Eluvathingal D., Chandrasekhar, Jayaraman, Schleyer, Paul von R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 752 KB

english, 1979

5

6,9-Pyridazaprostacyclin and derivatives: the first "aromatic" prostacyclins

Nicolaou, K. C., Barnette, W. E., Magolda, R. L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 410 KB

english, 1979

6

Solid-state spectroelectrochemistry of crosslinked donor bound polymer films

Kaufman, Frank B., Engler, Edward M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 407 KB

english, 1979

7

Thermolysis of 2-methylazulene(1-carbon-13) and mechanism of the azulene to naphthalene rearrangement

Alder, Roger W., Whiteside, Robert W., Whittaker, Graham, Wilshire, Colin

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 542 KB

english, 1979

8

CpM(CO)2(ligand) (Cp = cyclopentadienyl, M = metal) complexes

Schilling, Birgitte E. R., Hoffmann, Roald, Lichtenberger, Dennis L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 847 KB

english, 1979

9

Ion thermochemistry of low-volatility compounds in the gas phase. 1. Intrinsic basicities of .alpha.-amino acids

Meot-Ner, Michael, Hunter, Edward P., Field, Frank H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 556 KB

english, 1979

10

Proton exchange and temperature studies of pyrazole in dimethyl-d6 sulfoxide by carbon-13 NMR

Litchman, William M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 389 KB

english, 1979

11

A copper(I) derivative of a ferraborane: preparation, crystal, and molecular structure of Cu[P(C6H5)3]2B5H8Fe(CO)3

Mangion, M., Ragaini, J. D., Schmitkons, T. A., Shore, S. G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 299 KB

english, 1979

12

A study of the stereochemistry at iron of electrophilic cleavage of the iron-carbon .sigma. bond in methyl(.eta.5-1-methyl-3-phenylcyclopentadienyl)carbonyl(triphenylphosphine)iron(II)

Attig, Thomas G., Teller, Raymond G., Wu, Su-Miau, Bau, Robert, Wojcicki, Andrew

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.27 MB

english, 1979

13

Electrophilic substitution at saturated carbon. 52. A model for the proton transfer steps of biological transamination and the effect of a 4-pyridyl group on the base-catalyzed racemization of a carbon acid

Jaeger, David A., Broadhurst, Michael D., Cram, Donald J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 2.26 MB

english, 1979

14

Facile attachment of transition metal complexes to graphite electrodes coated with polymeric ligands. Observation and control of metal-ligand coordination among reactants confined to electrode surfaces

Oyama, Noboru, Anson, Fred C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 373 KB

english, 1979

15

Chemistry of singlet oxygen. 30. The unstable primary product of tocopherol photooxidation

Clough, R. L., Yee, B. G., Foote, C. S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 512 KB

english, 1979

16

Derivatives of heteropolyanions. 1. Organic derivatives of W12SiO404-, W12PO403-, and Mo12SiO404-

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 306 KB

english, 1979

17

Heats of hydrogenation and formation of linear alkynes and a molecular mechanics interpretation

Rogers, Donald W., Dagdagan, Orlando A., Allinger, Norman L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 801 KB

english, 1979

18

Tetracyclines. 9. Total synthesis of dl-terramycin

Muxfeldt, Hans, Haas, George, Hardtmann, Goetz, Kathawala, Faizulla, Mooberry, Jared B., Vedejs, Edwin

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.82 MB

english, 1979

19

Optical activity of saturated ketones. Ab initio localized orbital analysis of a model ketone in the random-phase approximation

Bouman, Thomas D., Voigt, Bjoern, Hansen, Aage E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.13 MB

english, 1979

20

The origin of the red shift of the absorption spectra of aggregated chlorophylls

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 440 KB

english, 1979

21

Substitution reactions which proceed via radical anion intermediates. 20. Replacement of the nitro group by hydrogen

Kornblum, Nathan, Carlson, Stephen C., Smith, Ronald G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.51 MB

english, 1979

22

Metalation of arenechromium tricarbonyl complexes and electrophilic trapping of the complexed phenyllithium intermediate

Semmelhack, M. F., Bisaha, J., Czarny, M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 440 KB

english, 1979

23

Biosynthesis of the antibiotic granaticin

Snipes, Carl E., Chang, Ching-Jer, Floss, Heinz G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 830 KB

english, 1979

24

Light-initiated redox reactions in functional micellar assemblies. 2. Dynamics in europium(III) surfactant solutions

Moroi, Yoshikiyo, Infelta, Pierre P., Graetzel, Michael

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 804 KB

english, 1979

25

Effect of protonation of nitrogen-containing organic molecules on the reactivity toward positronium

Kobayashi, Yoshinori, Nomizu, Tsutomu, Ujihira, Yusuke

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 438 KB

english, 1979

26

Phosphoranes as intermediates in the acid hydrolysis of acyclic phosphonate esters: evidence from oxygen exchange

Sigal, I., Westheimer, F. H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 383 KB

english, 1979

27

Dynamic equilibrium between ion pairs of aromatic [9]annulene anion and of olefinic nonafulvene structure

Boche, Gernot, Heidenhain, Frank

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 301 KB

english, 1979

28

Picosecond studies of excited-state protonation and deprotonation kinetics. The laser pH jump

Clark, J. H., Shapiro, S. L., Campillo, A. J., Winn, K. R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 424 KB

english, 1979

29

Chemistry of polymer-bound o-benzyne. Frequency of encounter between substituents on crosslinked polystyrenes

Mazur, Stephen, Jayalekshmy, P.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 906 KB

english, 1979

30

Intramolecular excimer-forming probes of aqueous micelles

Emert, Jack, Behrens, Carl, Goldenberg, Merrill

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 289 KB

english, 1979

31

(C2)-Dioxa-c20-octaquinane, a heterocyclic trisecododecahedrane

Balogh, Douglas, Begley, William J., Bremner, David, Wyvratt, Matthew J., Paquette, Leo A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 388 KB

english, 1979

32

Conformational analysis of trans-1,2-dibromocyclohexane by low-temperature cyclic voltammetry

Klein, Andrew J., Evans, Dennis H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 298 KB

english, 1979

33

Conformational analysis by nuclear magnetic resonance spectroscopy: Nitrogen-15 NMR of a cyclic pentapeptide

Williamson, Kenneth L., Pease, Lila G., Roberts, John D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 392 KB

english, 1979

34

Solute-solvent interactions in the ground state and in electronic excited states. The dipolar aprotic to polar protic solvent blue shift of nitroaromatics

Haberfield, Paul, Lux, Michael S., Jasser, Ira, Rosen, Douglas

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 383 KB

english, 1979

35

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 672 KB

english, 1979

36

Evidence for a radical-anion pathway of a phenylcyclopropyl ring cleavage in the presence of potassium tert-butoxide

Newcomb, Martin, Seidel, Terry, McPherson, Mary B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 297 KB

english, 1979

37

Light-initiated electron transfer in functional surfactant assemblies. 1. Micelles with transition metal counterions

Moroi, Yoshikiyo, Braun, Andre M., Graetzel, Michael

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 727 KB

english, 1979

38

Effect of carbon atom pyramidalization on the bonding in ethylene

Volland, Walter V., Davidson, Ernest R., Borden, Weston Thatcher

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 751 KB

english, 1979

39

Two conformations of the pentadienyl radical

Griller, D., Ingold, K. U., Walton, J. C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 307 KB

english, 1979

40

Rhenium formyl and carboxy complexes derived from the cyclopentadienyl(dicarbonyl)nitrosylrhenium(1+) cation: models for the Fischer-Tropsch and water gas shift reactions

Casey, Charles P., Andrews, Mark A., Rinz, James E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 426 KB

english, 1979

41

Biosynthesis of the C15 macrolide antibiotics. 1. Biochemical origin of the four oxygen atoms in brefeldin A

Mabuni, Clayton T., Garlaschelli, Luigi, Ellison, Robert A., Hutchinson, C. Richard

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.09 MB

english, 1979

42

Calorimetric disproportionation enthalpies

Stevenson, Gerald R., Williams, Elmer, Caldwell, Gary

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 394 KB

english, 1979

43

Coordination chemistry of microbial iron transport compounds. 11. Solution equilibriums and electrochemistry of ferric rhodotorulate complexes

Carrano, Carl J., Cooper, Stephen R., Raymond, Kenneth N.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 712 KB

english, 1979

44

The proton chemical shift in polycrystalline decarbonyldihydrotriosmium, dodecacarbonyltetrahydrotetraruthenium, and dodecacarbonyltetrahydrotetraosmium

Nicol, A. T., Vaughan, R. W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 361 KB

english, 1979

45

Carbon monoxide exchange in 1,2-dimethyl-1,3,2-diazaphosphenium tetracarbonyliron cation

Bennett, Dennis W., Parry, Robert W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 422 KB

english, 1979

46

Sensitivity enhancement in natural abundance proton-coupled nitrogen-15 NMR spectra using the selective population transfer method

Jakobsen, Hans J., Brey, Wallace S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 281 KB

english, 1979

47

The .sigma. strength of ligands coordinated to transition metal ions

Burdett, Jeremy K.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 537 KB

english, 1979

48

Conformational influences on electronic spectra and structure. Polymorphs of N-(p-chlorobenzylidene)-p-chloroaniline

Bernstein, J., Anderson, T. E., Eckhardt, C. J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 527 KB

english, 1979

49

A comparison of intermolecular and intramolecular excimer formation in detergent solutions. Temperature effects and microviscosity measurements

Turro, Nicholas J., Aikawa, Masayuki, Yekta, Ahmad

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 400 KB

english, 1979

50

Masthead

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 241 KB

english, 1979

51

The rate of site-site interactions in functionalized polystyrenes

Rebek, Julius, Trend, John E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 143 KB

english, 1979

52

Theoretical relationship between diamagnetic susceptibility exaltation and aromatic stabilization

Aihara, Junichi

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 376 KB

english, 1979

53

Tricyclobutabenzene

Nutakul, Wutichai, Thummel, Randolph P., Taggart, Austin D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 296 KB

english, 1979

54

Preparation and characterization of organoiron secondary alkoxycarbene complexes

Cutler, Alan R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 424 KB

english, 1979

55

Anion complexes of ferrous porphyrins

Mincey, Terry, Traylor, T. G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 270 KB

english, 1979

56

Formation of the trihalide ion Cl3- in the gas phase

Robbiani, Richard, Franklin, J. L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 250 KB

english, 1979

57

Solvation of alkali metal cations of arylmethyl anions by ethereal solvents

O'Brien, Daniel H., Russell, Charles R., Hart, Alan J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 938 KB

english, 1979

58

Synthesis and characterization of (pentafluorosulfur)acetylenes

Berry, A. D., De Marco, R. A., Fox, W. B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 305 KB

english, 1979

59

Ligand exchange in TaX(.eta.4-naphthalene)(Me2PC2H4PMe2)2. The pentagonal bipyramid to monocapped trigonal prism traverse

Albright, J. O., Datta, S., Dezube, B., Kouba, J. K., Marynick, D. S., Wreford, S. S., Foxman, Bruce M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.17 MB

english, 1979

60

Preparation of new palladium dioxygen complexes using superoxide ion

Suzuki, Hiroharu, Mizutani, Kyoichiro, Morooka, Yoshihiko, Ikawa, Tsuneo

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 258 KB

english, 1979

61

Size and asymmetry of spatial distributions for unperturbed triglycerides

Mattice, Wayne L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 559 KB

english, 1979

62

Reactivity of superoxide ion with carbonyl compounds in aprotic solvents

Gibian, Morton J., Sawyer, Donald T., Ungermann, Timothy, Tangpoonpholvivat, R., Morrison, Mark M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 646 KB

english, 1979

63

Water-soluble polyphosphazenes as carrier molecules for iron(III) and iron(II) porphyrins

Allcock, Harry R., Greigger, Paul P., Gardner, James E., Schmutz, James L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 908 KB

english, 1979

64

Theoretical studies of the reactions of the sulfur-sulfur bond. 2. Binding and reactions with Group 1A and 2A metals

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 921 KB

english, 1979

65

The role of solvation and choice of anion in controlling the thermodynamic stability of the cyclooctatetraene and anthracene dianions

Stevenson, Gerald R., Valentin, Jose, Williams, Elmer, Caldwell, Gary, Alegria, Antonio E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 554 KB

english, 1979

66

Carbonium ions in solution. 9. The relationship between carbocations in superacid and solvolysis transition states

Arnett, Edward M., Petro, Craig, Schleyer, Paul von R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 659 KB

english, 1979

67

Spectroscopic studies on model compounds of the phytochrome chromophore. Protonation and deprotonation of biliverdin dimethyl ester

Margulies, Leon, Stockburger, Manfred

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 266 KB

english, 1979

68

A time-dependent cyclodextrin induced perturbation of ionic equilibriums across a carbohydrate membrane

Siegel, Brock, Eberlein, Diane, Rifkin, Daniel, Davis, Kathleen A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 414 KB

english, 1979

69

Enzyme-assisted semisynthesis of human insulin

Inouye, Ken, Watanabe, Kunio, Morihara, Kazuyuki, Tochino, Yoshihiro, Kanaya, Takashi, Emura, Junji, Sakakibara, Shumpei

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 279 KB

english, 1979

70

Substitution reactions which proceed via radical anion intermediates. 21. Rearrangements in the reaction of .beta.-arylated nitroparaffins with the sodium salt of methanethiol

Kornblum, Nathan, Widmer, Joerg, Carlson, Stephen C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 953 KB

english, 1979

71

Dynamic stereochemistry and steric effects in overcrowded ethylenes. Conformational behavior of dixanthylenes

Agranat, Israel, Tapuhi, Yitzhak

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 987 KB

english, 1979