Volume 101; Issue 8

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Journal of the American Chemical Society
Volume 101; Issue 8

Journal of the American Chemical Society

Volume 101; Issue 8

1

Biradicaloid intermediates in photochemistry: spectroscopic and kinetic study of 1,4-perinaphthadiyl and related 1,8-naphthoquinodimethans

Gisin, Markus, Rommel, Erika, Wirz, Jakob, Burnett, Michael N., Pagni, Richard M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 465 KB

english, 1979

2

Nickel-induced conversion of carbon-oxygen into carbon-carbon bonds. One-step transformations of enol ethers into olefins and aryl ethers into biaryls

Wenkert, Ernest, Michelotti, Enrique L., Swindell, Charles S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 262 KB

english, 1979

3

Solvation. A molecular dynamics study of a dipeptide in water

Rossky, Peter J., Karplus, Martin

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 3.20 MB

english, 1979

4

Preparation of vinblastine, vincristine, and leurosidine, antitumor alkaloids from Catharanthus species (Apocynaceae)

Mangeney, Pierre, Zo Andriamialisoa, R., Langlois, Nicole, Langlois, Yves, Potier, Pierre

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 384 KB

english, 1979

5

Spectrophotometric determination of the proton-dependent stability constant of ferric enterobactin

Harris, Wesley R., Carrano, Carl J., Raymond, Kenneth N.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 281 KB

english, 1979

6

Synthesis of cyclopropane derivatives from olefins by the reaction with organic gem-dihalides and copper

Kawabata, Nariyoshi, Kamemura, Ichiro, Naka, Michiharu

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 957 KB

english, 1979

7

Aspects of artificial photosynthesis. Photoionization and electron transfer in dihexadecyl phosphate vesicles

Escabi-Perez, Jose R., Romero, Alejandro, Lukac, Sava, Fendler, Janos H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 421 KB

english, 1979

8

Multiple emission from sulfur complexes of rhodium(III) and iridium(III)

Merrill, James T., DeArmond, M. Keith

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.26 MB

english, 1979

9

Tetracyclines. 10. Chemical-structural properties of tetracycline derivatives. 5. A total synthesis and structural aspects of racemic 8-oxygenated tetracyclines

Glatz, B., Helmchen, G., Muxfeldt, H., Porcher, H., Prewo, R., Senn, J., Stezowski, J. J., Stojda, R. J., White, D. R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.69 MB

english, 1979

10

Nickel atom promoted dimerization of dimethylfulvene. A formal [6 + 6] cycloaddition

Nguyen Hao,, Sawyer, Jeffery F., Sayer, Brian G., McGlinchey, Michael J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 284 KB

english, 1979

11

Silyl ketone chemistry. A new regiospecific route to silyl enol ethers

Reich, Hans J., Rusek, Jay J., Olson, Richard E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 398 KB

english, 1979

12

Regiocontrolled anodic cyanation of nitrogen heterocycles. Pyrroles and indoles

Yoshida, Kunihisa

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 811 KB

english, 1979

13

Derivatives of heteropolyanions. 2. Metal-metal-bonded derivatives

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 423 KB

english, 1979

14

Photoselected fluorescence detected circular dichroism

Lobenstine, Eric W., Turner, Douglas H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 385 KB

english, 1979

15

A facile ring-opening reaction of furfuryl carbanion. Regioselective generation of di- or trianionic enolates

Atsumi, Kunio, Kuwajima, Isao

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 431 KB

english, 1979

16

Synthesis and cyclization reactions of alkynyl (.eta.5-cyclopentadienyltricarbonylmolybdenum and -tungsten) complexes

Watson, Patricia L., Bergman, Robert G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.13 MB

english, 1979

17

Syntheses, properties, and photoelectron spectra of substituted and layered [2.2](2,6)pyridinoparacyclophanes

Reingold, I. D., Schmidt, W., Boekelheide, V.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.06 MB

english, 1979

18

New evidence for the involvement of monomeric silicon difluoride in reactions with olefins

Thompson, J. C., Wright, A. P. G., Reynolds, W. F.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 265 KB

english, 1979

19

Photopolymerization in chiral crystals. 3. Toward an "absolute" asymmetric synthesis of optically active dimers and polymers with quantitative enantiomeric yield

Addadi, Lia, Lahav, Meir

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 578 KB

english, 1979

20

Metal alkyls as precursors for polylithium organic compounds. A high yield synthesis for "C2Li6"

Shimp, Lawrence A., Lagow, Richard J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 412 KB

english, 1979

21

2,2-Dimethylisoindene and 5,5-dimethylbenzobicyclo[2.1.0]pent-2-ene

Dolbier, William R., Matsui, Kazumasa, Dewey, Harry J., Horak, David V., Michl, Josef

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 571 KB

english, 1979

22

Iron-catalyzed oxidative decarboxylation of benzoylformic acid

Siegel, Brock, Lanphear, Jane

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 306 KB

english, 1979

23

An amplified sector rule for electric dipole-allowed transitions

Weigang, Oscar E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.41 MB

english, 1979

24

Experimental determination of the relative rates of rotation, cleavage, closure, and 1,5-hydrogen shift for 3-methyl-1,4-pentanediyl. Evidence for 1,4 biradicals as common intermediates from different precursors, 3,4-(and 3,6-)dimethyl-3,4,5,6-tetrahydropyridazines and 1,2-dimethylcyclobutanes

Dervan, Peter B., Uyehara, Tadao, Santilli, Donald S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 896 KB

english, 1979

25

Bicyclic phosphoranes as precursors of mono- or bidentate eight-membered cyclic ligands. Coordination compounds with the metal in a cradle

Pradat, Christian, Riess, Jean G., Bondoux, Daniel, Mentzen, Bernard F., Tkatchenko, Igor, Houalla, Doureid

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 288 KB

english, 1979

26

Vibrational analysis by electron paramagnetic resonance spectroscopy. The isopropyl radical

Griller, D., Preston, K. F.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 697 KB

english, 1979

27

Theoretical studies of the oxy anionic substituent effect

Steigerwald, Michael L., Goddard, William A., Evans, David A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 504 KB

english, 1979

28

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 901 KB

english, 1979

29

Rates and equilibriums for the inactivation of muscle aldolase by an active site directed Michael reaction

Motiu-DeGrood, Rossana, Hunt, William, Wilde, Joyce, Hupe, D. J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 958 KB

english, 1979

30

Electron transfer processes in the photochemistry of .beta.-(dimethylamino)propiophenone

Encinas, M. V., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 827 KB

english, 1979

31

Ion cyclotron resonance mass spectrometric and ab initio studies of the structure and mechanism of formation of protonated dimers in simple carbonyl compounds XYCO (X or Y = hydrogen or fluorine)

Hagler, A. T., Karpas, Z., Klein, F. S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 783 KB

english, 1979

32

Structures and energies of cumulene carbenes

Dykstra, Clifford E., Parsons, Craig A., Oates, Caren L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 509 KB

english, 1979

33

A general methodology for pseudoguaiane synthesis: total synthesis of (.+-.)-damsinic acid and (.+-.)-confertin

Wender, Paul A., Eissenstat, Michael A., Filosa, Michael P.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 391 KB

english, 1979

34

A bisphenylnitrene complex of molybdenum with a bent nitrene ligand. Preparation and structure of cis-bis(phenylnitrene)bis(diethyldithiocarbamato)molybdenum

Haymore, Barry L., Maatta, Eric A., Wentworth, R. A. D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 767 KB

english, 1979

35

Electron-transfer reactions of metallocenes. Influence of metal oxidation state on structure and reactivity

Holloway, John D. L., Geiger, William E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 874 KB

english, 1979

36

Flash vacuum pyrolysis studies. 7. Structure and origin of the onion lachrymatory factor. A microwave study

Block, Eric, Penn, Robert E., Revelle, Larry K.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 306 KB

english, 1979

37

Quantum and statistical mechanical studies of liquids. 3. Deriving intermolecular potential functions for the water dimer from ab initio calculations

Jorgensen, William L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 797 KB

english, 1979

38

Solution stereochemistry of cyclophosphamide and rigid model analogs

White, D. W., Gibbs, D. E., Verkade, J. G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 860 KB

english, 1979

39

Decomposition of the 1,3-butadiene radical cation on the microsecond to picosecond time scale

Russell, D. H., Gross, M. L., Van der Greef, J., Nibbering, N. M. M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 643 KB

english, 1979

40

Oxidations and oxygen transfers effected by a flavin N(5)-oxide. A model for flavin-dependent monooxygenases

Rastetter, W. H., Gadek, T. R., Tane, J. P., Frost, J. W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 566 KB

english, 1979

41

Avoparcin

McGahren, W. J., Martin, J. H., Morton, G. O., Hargreaves, R. T., Leese, R. A., Lovell, F. M., Ellestad, G. A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 438 KB

english, 1979

42

Geometrical structure and energetics of Closs's diradical: 1,3-cyclopentadiyl

Conrad, Morgan P., Pitzer, Russell M., Schaefer, Henry F.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 273 KB

english, 1979

43

A radical-chain mechanism in substitution reactions of (unsaturated alkyl) metal carbonyl complexes

Fabian, Benedict D., Labinger, Jay A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 326 KB

english, 1979

44

Penems. 1. Penem formation via a novel oxidative addition process mediated by copper(I)

DiNinno, Frank, Linek, Ernest V., Christensen, B. G.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 313 KB

english, 1979

45

Is formamide planar or nonplanar?

Carlsen, Norman R., Radom, Leo, Riggs, Noel V., Rodwell, William R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 302 KB

english, 1979

46

Stereochemical tests of cyclic 1,1-dialkyldiazene fragmentation reactions. Thermal decomposition of N-(cis-(and trans-)2,3-(and 2,5-)dimethylpyrrolidine)nitrenes

Dervan, Peter B., Uyehara, Tadao

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 899 KB

english, 1979

47

NMR spectroscopic studies on kinetics and thermodynamics of reversible dissociation reactions. 6. Ionization of tropylium azide in liquid sulfur dioxide and selective migration of the azide ligand in less polar solvents

Feigel, Martin, Kessler, Horst, Leibfritz, Dieter, Walter, Axel

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 699 KB

english, 1979

48

Reactivity of 1,3-dipoles in aqueous solution. 3. Theoretical study on the reactions of 1,3-dipoles with nucleophiles. The fulminic acid-hydroxide ion system

Leroy, G., Nguyen, M. T., Sana, M., Dignam, K. J., Hegarty, A. F.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 661 KB

english, 1979

49

Application of ab initio molecular orbital calculations to the structural moieties of carbohydrates. 5. The geometry of the hydrogen bonds

Newton, M. D., Jeffrey, G. A., Takagi, Shozo

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 794 KB

english, 1979

50

Photochemical heavy-atom effect. 8. Multipathway photodimerization of 2-methylthianaphthene 1,1-dioxide. An example of a heavy-atom effect on intersystem crossing in a 1,4 diradical

Hopkinson, Michael J., Schloman, William W., Plummer, Benjamin F., Wenkert, E., Raju, M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 997 KB

english, 1979

51

Energy transfer from triplet aromatic hydrocarbons to terbium(3+) and europium(3+) in aqueous micellar solutions

Almgren, M., Grieser, F., Thomas, J. K.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 748 KB

english, 1979

52

Investigation of the basis of the valence shell electron pair repulsion model by ab initio calculation of geometry variations in a series of tetrahedral and related molecules

Schmiedekamp, Ann, Cruickshank, D. W. J., Skaarup, Steen, Pulay, Peter, Hargittai, Istvan, Boggs, James E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.03 MB

english, 1979

53

Photochemical reaction of dicyanoanthracene with acetonitrile in the presence of an aliphatic amine. A novel photochemical amination

Ohashi, Mamoru, Kudo, Hitoshi, Yamada, Shuzo

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 326 KB

english, 1979

54

The chemistry of tetrahedral intermediates. 4. Hemiorthothiolate ester anions - RC(OR')2S- +Na. A novel class of thermally stable tetrahedral intermediates

Khouri, Farid, Kaloustian, Moses K.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 409 KB

english, 1979

55

Resonance Raman studies on pyrocatechase

Que, Lawrence, Heistand, Robert H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 421 KB

english, 1979

56

Unusual substituent and multiplicity effects in carbenic ring expansion and substitution reactions of benzenes with 3-diazo-2,5-diphenylpyrrole

Nagarajan, M., Shechter, H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 440 KB

english, 1979

57

Rapid scanning stopped-flow absorption studies of the effect on tryptophanase of a change in pH or potassium(1+) ion concentration: evidence for a slow conformational change

June, David S., Kennedy, Barbara, Pierce, T. H., Elias, Sami V., Halaka, Folim, Behbahani-Nejad, Iraj, El Bayoumi, Ashraf, Suelter, Clarence H., Dye, James L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 284 KB

english, 1979

58

Investigation of the zeolite catalyzed alkylation of toluene using carbon-13 nuclear magnetic resonance

Sefcik, Michael D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 824 KB

english, 1979

59

A study of the synthesis and properties of [2.2.2.2](1,2,4,5)cyclophane

Gray, Richard, Boekelheide, V.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.23 MB

english, 1979

60

Enthalpies of interaction of aliphatic ketones with polar and nonpolar solvents

Saluja, P. P. S., Peacock, L. A., Fuchs, R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 704 KB

english, 1979

61

Intramolecular kinetic isotope effect in gas-phase proton-transfer reactions

Wellman, Keith M., Victoriano, Maria E., Isolani, Paulo C., Riveros, Jose M.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 306 KB

english, 1979

62

Novel reactions of dioxygen in organometallic chemistry. Hydrogen atom abstraction vs. dimerization of the 19-electron complexes .eta.5-cyclopentadienyliron(I) .eta.6-arene

Astruc, Didier, Roman E., Enrique, Hamon, Jean Rene, Batail, Patrick

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 454 KB

english, 1979

63

Carboxylic and phosphate esters of .alpha.-fluoro alcohols

Ortiz de Montellano, Paul R., Vinson, Wayne A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 430 KB

english, 1979

64

Stereochemically nonrigid silanes, germanes, and stannanes. 4. Chiral silylcyclopentadienes: new evidence for a 1,2 (1,5) metallotropic shift

Bonny, Alan, Stobart, Stephen R.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 344 KB

english, 1979

65

Chemically induced dynamic nuclear polarization from the selective recombination of radical pairs in micelles

Hutton, Richard S., Roth, Heinz D., Kraeutler, Bernhard, Cherry, William R., Turro, Nicholas J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 269 KB

english, 1979

66

Ketyls of cyclic .alpha.,.beta.-unsaturated ketones. 2. Formation of radical anions by electron transfer using trimethylsilylsodium or dimethyl sulfoxide-potassium tert-butoxide

Russell, Glen A., Malatesta, V., Morita, T., Osuch, C., Blankespoor, R. L., Trahanovsky, Kathleen D., Goettert, E.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 604 KB

english, 1979

67

Secondary ion mass spectrometry of molecular solids. Cluster formation during ion bombardment of frozen water, benzene, and cyclohexane

Lancaster, Gerald M., Honda, Fumihiro, Fukuda, Yasuo, Rabalais, J. W.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 912 KB

english, 1979

68

Syn stereospecificity in the SN2' reaction of an acyclic allylic chloride with secondary amines

Magid, Ronald M., Fruchey, O. Stanley

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 903 KB

english, 1979

69

Benzylic organolithium carbanion reactivity. 3. Kinetic studies with neopentyl halides and benzyl fluoride

Zieger, H. E., Mathisen, Donald

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 302 KB

english, 1979

70

Radical and ionic reaction pathways in the thermal decomposition of diacyl peroxides

Taylor, K. Grant, Govindan, C. K., Kaelin, Milton S.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.19 MB

english, 1979

71

A pair-specific osmium reagent for polynucleotides

Ford, H., Chang, C. H., Behrman, E. J.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 276 KB

english, 1979

72

.sigma. and .pi. Components of substituent effects in saturated systems. Monosubstituted methanes

Wiberg, Kenneth B.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 279 KB

english, 1979

73

The inertial contribution to vibrational optical activity in methyl torsion modes

Barron, L. D., Buckingham, A. D.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 998 KB

english, 1979

74

Minimal basis set description of the structure and properties of liquid water

Jorgensen, William L.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 786 KB

english, 1979

75

Masthead

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 119 KB

english, 1979

76

Activation of water molecule. 2. Generation of strong hydroxo bases by the reaction of water with platinum(0) phosphine complexes and the applications as catalysts for hydrogen-deuterium exchange and hydration reactions

Yoshida, Toshikatsu, Matsuda, Tadao, Okano, Tamon, Kitani, Tetsumi, Otsuka, Sei

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 1.37 MB

english, 1979

77

Dominant double rotation in the thermally induced 1,2,4-trimethylspiropentane geometric isomerization

Gajewski, Joseph J., Weber, Robert J., Chang, Ming Jing

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 987 KB

english, 1979

78

Structure elucidation by high resolution mass spectrometry of a highly modified nucleoside from mammalian transfer RNA. N-[(9-.beta.-D-Ribofuranosyl-2-methylthiopurin-6-yl)carbamoyl]threonine

Yamaizumi, Z., Nishimura, S., Limburg, Klaus, Raba, Manfred, Gross, Hans J., Crain, P. F., McCloskey, James A.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 278 KB

english, 1979

79

Electrocyclic ring opening of the cyclobutene radical cation

Gross, Michael L., Russell, David H.

Journal:

Journal of the American Chemical Society

Year:

1979

Language:

english

File:

PDF, 731 KB

english, 1979

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