Volume 103; Issue 1

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Journal of the American Chemical Society
Volume 103; Issue 1

Journal of the American Chemical Society

Volume 103; Issue 1

1

First manganese(III) spin crossover, first d4 crossover. Comment on cytochrome oxidase

Sim, P. Greig, Sinn, Ekk

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 395 KB

english, 1981

2

Total synthesis of (.+-.)-isocomene and related studies

Pirrung, Michael C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 859 KB

english, 1981

3

Formation of superoxide ion from singlet oxygen. Use of a water-soluble singlet oxygen source

Saito, Isao, Matsuura, Teruo, Inoue, Kenzo

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 431 KB

english, 1981

4

Rational mechanism for homogeneous hydrogenation of carbon monoxide to alcohols, polyols, and esters

Fahey, Darryl R.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 744 KB

english, 1981

5

Interligand steric effects in metal complexes in solution studied through the residual circular dichroism of the d-d transitions: application to tetraaminecobalt(III)-amino acid complexes

Job, Robert, Schipper, Pieter E.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 511 KB

english, 1981

6

Kinetics and mechanism of the conjugate addition of lithium dimethylcuprate to .alpha.,.beta.-unsaturated ketones

Krauss, Susan Ruth, Smith, Stanley G.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.13 MB

english, 1981

7

Minor and trace sterols in marine invertebrates. 19. Isolation, structure elucidation, and partial synthesis of 24-methylene-25-ethylcholesterol (mutasterol): first example of sterol side-chain bioalkylation at position 25

Li, Lian Niang, Sjoestrand, Ulf, Djerassi, Carl

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 575 KB

english, 1981

8

Photoresponsive crown ethers. 2. Photocontrol of ion extraction and ion transport by a bis(crown ether) with a butterfly-like motion

Shinkai, Seiji, Nakaji, Takahiro, Ogawa, Toshiyuki, Shigematsu, Kazuyoshi, Manabe, Osamu

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 669 KB

english, 1981

9

Transition-metal methylene complexes. 14. Reactions of an electron-rich dimetallacyclopropane with protic acids: synthesis and x-ray crystal structures of novel rhodium-methyl and -methylidyne complexes

Herrmann, Wolfgang A., Plank, Johann, Riedel, Doris, Ziegler, Manfred L., Weidenhammer, Klaus, Guggolz, Ernst, Balbach, Barbara

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.69 MB

english, 1981

10

High acylation rates and enantioselectivity with cyclodextrin complexes of rigid substrates

Trainor, George L., Breslow, Ronald

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 761 KB

english, 1981

11

Delocalized .pi. bonding in tetraazadiene metallocycles

Gross, Michal E., Trogler, William C., Ibers, James A.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 271 KB

english, 1981

12

A mild procedure for the generation of azomethine imines. Stereochemical factors in the intramolecular 1,3-dipolar addition of azomethine imines and a synthetic approach to saxitoxin

Jacobi, Peter A., Brownstein, Allen, Martinelli, Michael, Grozinger, Karl

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 437 KB

english, 1981

13

Reactions involving hydrogen peroxide, iodine, and iodate ion. 7. The smooth catalytic decomposition of hydrogen peroxide, mainly at 50.degree.C

Liebhafsky, Herman A., Furuichi, Ryusaburo, Roe, Glenn M.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 825 KB

english, 1981

14

Interaction of metal ions with streptonigrin. 1. Formation of copper(II) and zinc(II) complexes of the antitumor antibiotic

Hajdu, Joseph, Armstrong, Ellen C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 336 KB

english, 1981

15

Convenient thermal sources of .beta.-cyanoalkyl radicals from .alpha.-hydroxydiazenes

Nazran, Avtar S., Warkentin, John

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 273 KB

english, 1981

16

Alkylidene complexes from the reactions of transition-metal dianions with iminium salts: synthesis and spectral characterization of [Mo(CO)5CPh2]

Beatty, Richard P., Maher, John M., Cooper, N. John

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 315 KB

english, 1981

17

Rectifying interfaces using two-layer films of electrochemically polymerized vinylpyridine and vinylbipyridine complexes of ruthenium and iron on electrodes

Abruna, H. D., Denisevich, P., Umana, M., Meyer, Thomas J., Murray, Royce W.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 630 KB

english, 1981

18

CNDO/2-predicted charge alternation

Stolow, Robert D., Samal, Peter W., Giants, Thomas W.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 379 KB

english, 1981

19

A structural study of tris(.beta.-diketonate)europium(III) complexes in solution using magnetic circularly polarized luminescence spectroscopy

Richardson, Frederick S., Brittain, Harry G.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 905 KB

english, 1981

20

Redox properties of metalloporphyrin excited states, lifetimes, and related properties of a series of para-substituted tetraphenylporphine carbonyl complexes of ruthenium(II)

Rillema, D. P., Nagle, J. K., Barringer, L. F., Meyer, T. J.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 940 KB

english, 1981

21

2,2',5,5'-Tetramethyldistibolyl. A thermochromic distibine

Ashe, Arthur J., Butler, William, Diephouse, Timothy R.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 431 KB

english, 1981

22

The circular dichroism and absolute configuration of C3-chiral derivatives of cyclotriveratrylene

Collet, Andre, Gottarelli, Giovanni

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 262 KB

english, 1981

23

Masthead

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 109 KB

english, 1981

24

Ultraviolet absorption spectra and photochemical rearrangements of benzyl and tropylium cations in solid argon

Andrews, Lester, Keelan, Brian W.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 644 KB

english, 1981

25

3,3'-Bicyclopropenyl: evidence for novel long-range conjugation of .pi. orbitals

Greenberg, Arthur, Liebman, Joel F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 604 KB

english, 1981

26

The decomposition of bicyclic endoperoxides: an isomorphous synthesis of frontalin via 1,5-dimethyl-6,7-dioxabicyclo[3.2.1]octane

Wilson, R. Marshall, Rekers, John W.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 274 KB

english, 1981

27

Carbon-13 NMR spectra of carbonium ions in the solid state: the sec-butyl cation

Myhre, Philip C., Yannoni, Costantino S.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 402 KB

english, 1981

28

Collision-induced dissociation mass spectrometry: target gas effects upon scattering and charge exchange

Laramee, J. A., Cameron, D., Cooks, R. G.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 735 KB

english, 1981

29

Oxidation of dithiols by flavopapain

Fried, Herbert E., Kaiser, E. T.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 433 KB

english, 1981

30

Total synthesis of (.+-.)-lycodoline

Heathcock, Clayton H., Kleinman, Edward F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 239 KB

english, 1981

31

NMR study of molecular reorientation under fivefold symmetry - solid permethylferrocene

Wemmer, D. E., Ruben, D. J., Pines, A.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 637 KB

english, 1981

32

Silicon photocathode behavior in acidic vanadium(II)-vanadium(III) solutions

Heller, A., Lewerenz, H. J., Miller, B.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 295 KB

english, 1981

33

Total synthesis of (.+-.)-modhephene

Smith, Amos B., Jerris, Paula J.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 325 KB

english, 1981

34

Absence of internal return in the reaction of (4-nitrophenyl)nitromethane with amine bases in toluene solution. Implication on unusually large isotope effects reported for this reaction

Kresge, A. J., Powell, M. F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 279 KB

english, 1981

35

Carbon monoxide bridges two copper centers which experience a very short metal-metal proximity in [Cu2(tmen)2(.mu.-CO)(.mu.-PhCO2)](BPh4)

Pasquali, Marco, Floriani, Carlo, Gaetani-Manfredotti, Amelia, Guastini, Carlo

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 273 KB

english, 1981

36

Stereocontrolled synthesis of steroidal side chains

Dauben, William G., Brookhart, Todd

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 275 KB

english, 1981

37

High methane formation during the temperature-programmed decomposition in flowing hydrogen of supported mononuclear and polynuclear carbonyl complexes

Hucul, Dennis A., Brenner, Alan

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 407 KB

english, 1981

38

Crystal and molecular structure of the isobacteriochlorin: (2,3,7,8-tetrahydro-5,10,15,20-tetraphenylporphinato)(pyridine)zinc(II) benzene solvate

Barkigia, K. M., Fajer, J., Spaulding, L. D., Williams, G. J. B.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 710 KB

english, 1981

39

Interaction frontier orbitals

Fukui, Kenichi, Koga, Nobuaki, Fujimoto, Hiroshi

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 252 KB

english, 1981

40

Deuterium magnetic resonance study of .alpha.,.omega.-dicarboxylic acid guests in disk micelles of varied bilayer thickness

Forrest, Bruce J., De Carvalho, Laura Hecker, Reeves, L. W., Rodger, Charles

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 282 KB

english, 1981

41

Diaryltetraoxypersulfuranes: preparation, characterization, and reactions

Lam, William Y., Martin, J. C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 996 KB

english, 1981

42

Reduction of bis(histidine)hemin; model for the proton-coupled reduction of hemoproteins

Baldwin, David A., Campbell, Vivien M., Carleo, Luigi A., Marques, Helder M., Pratt, John M.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 448 KB

english, 1981

43

Synthesis, structure, and stability of (i,o)-bicyclo[6.2.2]dodeca-9,11-dienes. Generation of unusually expanded carbon-carbon-carbon bond angles

Gassman, Paul G., Hoye, Rebecca C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 385 KB

english, 1981

44

The isolated molecule approach. Theoretical studies of the inductive effect

Topsom, Ronald D.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 645 KB

english, 1981

45

Kinetics of the reaction of (4-nitrophenyl)nitromethane with tetramethylguanidine in toluene

Caldin, E. F., Mateo, S., Warrick, P.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 411 KB

english, 1981

46

Carbon-13 chemical shifts in solid metal sandwich compounds

Wemmer, D. E., Pines, A.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 381 KB

english, 1981

47

Kinetics of free radicals produced by infrared multiphoton-induced decompositions. 1. Reactions of allyl radicals with nitrogen dioxide and bromine

Slagle, Irene R., Yamada, Fumiaki, Gutman, David

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.41 MB

english, 1981

48

An unexpectedly strong hydrogen bond: ab initio calculations and spectroscopic studies of amide-fluoride systems

Emsley, John, Jones, Deborah J., Miller, Jack M., Overill, Richard E., Waddilove, Roland A.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 700 KB

english, 1981

49

Unimolecular reactions of ionized methyl acetate and its enol: mechanism for the enol to keto isomerization

Vajda, Judit Hegedus, Harrison, Alex G., Hirota, Akira, McLafferty, Fred W.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 500 KB

english, 1981

50

Heme asymmetry in deuterohemin-reconstituted cytochrome peroxidase

Satterlee, James D., Erman, James E.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 291 KB

english, 1981

51

Intramolecular electron transfer and dehalogenation of anion radicals. 3. Halobenzonitriles and cyanobenzyl halides

Neta, P., Behar, D.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 501 KB

english, 1981

52

Synthesis and structure of Cu5(BTA)6(t-C4H9NC)4, a mixed-valent copper-nitrogen cluster containing eta3-benzotriazolate

Himes, Vicky L., Mighell, Alan D., Siedle, Allen R.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 301 KB

english, 1981

53

A comparison of hypervalent bond polarizabilities in sulfuranes (10-S-4 species) and persulfuranes (12-S-6 species)

Lam, William Y., Duesler, Eileen N., Martin, J. C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 982 KB

english, 1981

54

Model approach to the pentagonal dodecahedrane. Synthesis and properties of a monoseco derivative

Paquette, Leo A., Balogh, Douglas W., Blount, John F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 375 KB

english, 1981

55

Natural correlation diagrams. A unifying theoretical basis for analysis of n orbital initiated ketone photoreactions

Bigot, Bernard, Devaquet, Alain, Turro, Nicholas J.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 740 KB

english, 1981

56

Low-temperature neutron diffraction studies of carbon-hydrogen-metal interactions in two tantalum-neopentylidene complexes: [Ta(CHCMe3)(PMe3)Cl3]2 [T = 110 K] and the first alkylidene/olefin complex, Ta(.eta.5-C5Me5)(CHCMe3)(.eta.2-C2H4)(PMe3) [T = 20 K]

Schultz, Arthur J., Brown, Richard K., Williams, Jack M., Schrock, Richard R.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.05 MB

english, 1981

57

Unusual photoisomerization of an "encased" .alpha.-diketone

Balogh, Douglas W., Paquette, Leo A., Engel, Peter, Blount, John F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 379 KB

english, 1981

58

Molecules with a helix structure. 3. Sulfur-bridged peri-naphthalenes: synthesis, conformational analysis, and photoelectron spectroscopy of the mono-, di-, and trisulfides of 1,8-dimethylnaphthalene

Guttenberger, Hans G., Bestmann, Hans J., Dickert, Franz L., Jorgensen, Flemming S., Snyder, James P.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.19 MB

english, 1981

59

Formation of vinyl halides from vinyl cations generated by acetylenic participation in biomimetic polyene cyclizations

Johnson, William S., Ward, Carl E., Boots, Sharon G., Gravestock, Michael B., Markezich, Ronald L., McCarry, Brian E., Okorie, Dominic A., Parry, Ronald J.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 1.58 MB

english, 1981

60

Isolation and characterization of bicycloendoperoxides derived from methyl linolenate

O'Connor, David E., Mihelich, Edward D., Coleman, Milton C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 299 KB

english, 1981

61

A new aqueous chemistry of organometallic, trinuclear cluster compounds of molybdenum

Bino, Avi, Cotton, F. Albert, Dori, Zvi

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 282 KB

english, 1981

62

A bridging acetyl group from the reaction of a dinuclear methyl complex with carbon monoxide

Longato, Bruno, Norton, Jack R., Huffman, John C., Marsella, John A., Caulton, Kenneth G.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 285 KB

english, 1981

63

Evidence for a novel carbene-carbene rearrangement of a new foiled methylene

Brinker, Udo H., Koenig, Lothar

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 437 KB

english, 1981

64

Computation of peptide-protein interactions. Catalysis by chymotrypsin: prediction of relative substrate reactivities

DeTar, DeLos F.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 531 KB

english, 1981

65

Cis-trans isomers of 12-S-6 species--dissociative permutational isomerization of a persulfurane

Michalak, Ronald S., Martin, J. C.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 270 KB

english, 1981

66

Resonance enhanced Raman identification of the zinc-oxygen bond in a horse liver alcohol dehydrogenase-nicotinamide adenine dinucleotide-aldehyde transient chemical intermediate

Jagodzinski, Paul W., Peticolas, Warner L.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 400 KB

english, 1981

67

A strategy for the total synthesis of jatrophone: synthesis of normethyljatrophone

Smith, Amos B., Guaciaro, Michael A., Schow, Steven R., Wovkulich, Peter M., Toder, Bruce H., Hall, Tse Wai

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 527 KB

english, 1981

68

Metal-hydrogen bond energies in protonated transition-metal complexes

Stevens, Amy E., Beauchamp, J. L.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 428 KB

english, 1981

69

Influence of nitrogen-14 on carbon-13 NMR spectra of solids

Hexem, J. G., Frey, M. H., Opella, S. J.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 470 KB

english, 1981

70

A metal ion complex of vitamin B1: the preparation and structure of Cd(thiamine)Cl3.0.6H2O

Cramer, Roger E., Maynard, Richard B., Ibers, James A.

Journal:

Journal of the American Chemical Society

Year:

1981

Language:

english

File:

PDF, 689 KB

english, 1981