Volume 105; Issue 15

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Journal of the American Chemical Society
Volume 105; Issue 15

Journal of the American Chemical Society

Volume 105; Issue 15

1

Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction

Kiel, William A., Lin, Gong Yu, Bodner, Gerardo S., Gladysz, J. A.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.73 MB

english, 1983

2

Catalytic alkyl group exchange reaction of primary and secondary amines

Murahashi, Shunichi, Yoshimura, Noriaki, Tsumiyama, Tatsuo, Kojima, Takeyuki

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.31 MB

english, 1983

3

NMR spectroscopy of cyclohexane. Gas-phase conformational kinetics

Ross, Brian D., True, Nancy S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 705 KB

english, 1983

4

A product study of 1-adamantyl and 1-bicyclo[2.2.2]octyl radicals in hydrocarbon solvents. An unusually large hydrogen isotope effect

Engel, Paul S., Chae, Woo Ki, Baughman, Sharon A., Marschke, Gregor E., Lewis, Edward S., Timberlake, Jack W., Luedtke, Alan E.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 706 KB

english, 1983

5

Rate constants for the reactions of free radicals with oxygen in solution

Maillard, B., Ingold, K. U., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 677 KB

english, 1983

6

Radical chain carriers in N-bromosuccinimide brominations

Walling, Cheves, El-Taliawi, Gamil M., Zhao, Chengxue

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 834 KB

english, 1983

7

Mechanism of carbon-carbon cleavage of cyclic 1,2-diketones with alkaline hydrogen peroxide. The acyclic mechanism and its application to the basic autoxidation of pyrogallol

Sawaki, Yasuhiko, Foote, Christopher S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 608 KB

english, 1983

8

Are the silacyclopentadienyl anion and the silacyclopropenyl cation aromatic?

Gordon, Mark S., Boudjouk, Philip, Anwari, Freidun

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 637 KB

english, 1983

9

Design and synthesis of a highly amphoteric condensed hydrocarbon with the highest reduction potential. Pentaleno[1,2,3-cd:4,5,6-c'd']diphenalene

Nakasuji, Kazuhiro, Yoshida, Keiji, Murata, Ichiro

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 297 KB

english, 1983

10

Total synthesis of (-)-maysine

Meyers, A. I., Babiak, K. A., Campbell, Arthur L., Comins, Daniel L., Fleming, Michael P., Henning, Rainer, Heuschmann, Manfred, Hudspeth, James P., Kane, John M.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.38 MB

english, 1983

11

Porphyrins. 44. Electronic states of cobalt, nickel, rhodium, and palladium complexes

Antipas, Artemis, Gouterman, Martin

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 721 KB

english, 1983

12

Description of conjugation and hyperconjugation in terms of electron distributions

Bader, R. F. W., Slee, T. S., Cremer, D., Kraka, E.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.92 MB

english, 1983

13

Biosynthesis of antibiotics of the virginiamycin family. 3. Biosynthesis of virginiamycin M1

Kingston, David G. I., Kolpak, Michael X., LeFevre, Joseph W., Borup-Grochtmann, Ingrid

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 675 KB

english, 1983

14

A large nylon capsule coated with a synthetic bilayer membrane. Permeability control of sodium chloride by phase transition of the dialkylammonium bilayer coating

Okahata, Yoshio, Lim, Han Jin, Nakamura, Genichi, Hachiya, Satoshi

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.94 MB

english, 1983

15

Electrochemical modulation of fluorescence from zinc tetraphenylporphyrin on electrode surfaces

Pflug, Julie S., Faulkner, Larry R., Seitz, W. R.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 960 KB

english, 1983

16

Directionality of proton transfer in solution. Three systems of known angularity

Menger, F. M., Chow, J. F., Kaiserman, H., Vasquez, P. C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 874 KB

english, 1983

17

Photochemical and thermal stereomutations of 3-aryl-2-propenylideniminium salts

Childs, Ronald F., Dickie, Brian D.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 776 KB

english, 1983

18

Oxygen-17 NMR as a tool for studying oxygenated transition-metal derivatives: first direct oxygen-17 NMR observations of transition-metal-bonded peroxidic oxygen atoms. Evidence for the absence of oxo-peroxo oxygen exchange in molybdenum(VI) compounds

Postel, Michele, Brevard, Christian, Arzoumanian, Henri, Riess, Jean G.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 600 KB

english, 1983

19

Low-spin ferric porphyrin complexes: analysis of the electronic structure based on single-crystal electron spin resonance measurements

Byrn, Marianne P., Katz, Bradley A., Keder, Nancy L., Levan, Keith R., Magurany, Charles J., Miller, Kathleen M., Pritt, Jeffrey W., Strouse, Charles E.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 849 KB

english, 1983

20

Enol thioethers as enol substitutes. An alkylation sequence

Trost, Barry M., Lavoie, Alvin C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 2.18 MB

english, 1983

21

Effect of a polar substituent on olefin triplet lifetime

Caldwell, Richard A., Singh, Major

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 282 KB

english, 1983

22

Formation of a carbinolamine intermediate in the tertiary amine catalyzed enolization of oxaloacetic acid. An alternative mechanism for enolization

Bruice, Paula Yurkanis

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.87 MB

english, 1983

23

Heteronuclear 2D-NOE spectroscopy

Rinaldi, Peter L.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 199 KB

english, 1983

24

Facile synthesis of substituted brendanes via spirocyclopropane participation

Adam, Waldemar, Carballeira, Nestor, Peters, Eva Maria, Peters, Karl, Von Schnering, Hans Georg

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 249 KB

english, 1983

25

On the structure of anions derived from cycloheptatriene in the gas phase

White, Robert L., Wilkins, Charles L., Heitkamp, Jennifer J., Staley, Stuart W.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 324 KB

english, 1983

26

Stereoselective formation of cis-stilbene ozonide from the cosensitized electron-transfer photooxygenation of cis- and trans-2,3-diphenyloxiranes

Schaap, A. Paul, Siddiqui, Shahabuddin, Gagnon, Steven D., Lopez, Luigi

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 300 KB

english, 1983

27

Book reviews

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 2.68 MB

english, 1983

28

Reversible tautomerization of radical cations. Photoionization of 2-methoxyethanol and 3-methoxy-1-propanol

Biermann, H. W., Morton, Thomas Hellman

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 748 KB

english, 1983

29

Electric field gradient at iron in dicarbonyl complexes of (tetraphenylporphyrinato)- and (octamethyltetrabenzoporphyrinato)iron(II)

Reimer, Kenneth J., Sibley, Craig A., Sams, John R.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 417 KB

english, 1983

30

Alkylidene hydride complexes of tantalum and the polymerization of ethylene by diiodotris(trimethylphosphine)hydroneopentylidenetantalum [Ta(CHCMe3)(H)(PMe3)3I2]

Turner, H. W., Schrock, R. R., Fellmann, J. D., Holmes, S. J.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.23 MB

english, 1983

31

Kinetics and mechanism of oxidative addition and reductive elimination of hydrogen on triruthenium clusters

Bavaro, Lynn M., Montangero, Paolo, Keister, Jerome B.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 666 KB

english, 1983

32

2-Oxabicyclo[2.2.0]hexene/3-oxatricyclo[3.1.0.02,6]hexane isomerization

Eisenbarth, Philipp, Maas, Gerhard, Regitz, Manfred

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 269 KB

english, 1983

33

Additions and Corrections - Low-Valent Molybdenum Porphyrin Derivatives: Synthesis and Structure of a π-Bonded Adduct of Molbdenum(II) (meso-Tetra-p-tolylporphyrin)

De Cian, Andre, Colin, Jocelyne, Schappacher, Michel, Ricard, Louis, Weiss, Raymond

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 69 KB

english, 1983

34

Proton-transfer spectroscopy of 3-hydroxychromones. Extreme sensitivity to hydrogen-bonding perturbations

McMorrow, Dale, Kasha, Michael

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 267 KB

english, 1983

35

Masthead

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 120 KB

english, 1983

36

Structure and synthesis of 3-deoxy-D-glycero-pentos-2-ulose, an unusual sugar produced enzymatically from (ADP-ribosyl)histone H2B

Komura, Hajime, Iwashita, Takashi, Naoki, Hideo, Nakanishi, Koji, Oka, Jun, Ueda, Kunihiro, Hayaishi, Osamu

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 272 KB

english, 1983

37

The ionic hydrogen bond. 3. Multiple imidogen(1+)-oxygen (NH+...O) and methylidyne(.delta.+)-oxygen (CH.delta.+...O) bonds. Complexes of ammonium ions with polyethers and crown ethers

Meot-Ner, Michael

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 498 KB

english, 1983

38

Secondary isotope multiplet NMR spectroscopy of partially labeled entities. Carbon-13 SIMPLE NMR of carbohydrates

Christofides, John C., Davies, David B.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 869 KB

english, 1983

39

Hydrogen-bond stabilization of oxygen in hemoprotein models

Mispelter, Joel, Momenteau, Michel, Lavalette, Daniel, Lhoste, Jean Marc

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 284 KB

english, 1983

40

Selectivities of .pi.- and .sigma.-succinimidyl radicals in substitution and addition reactions. Response to Walling, El-Taliawi and Zhao

Skell, P. S., Tlumak, R. L., Seshadri, S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 889 KB

english, 1983

41

Novel products in the carbonylation of the triply bonded ditungsten hexaisopropoxide dipyridine adduct. 1. Synthesis and structure of the carbonylated triply bonded ditungsten hexaisopropoxide dipyridine adduct [(iso-PrO)3W(.mu.-CO)(.mu.-O-iso-Pr)W(O-iso-Pr)2py]2

Cotton, F. Albert, Schwotzer, Willi

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 386 KB

english, 1983

42

Photoaffinity labeling of bacteriorhodopsin with 3-([1-14C]diazoacetoxy)-trans-retinal

Sen, Ranjan, Widlanski, Theodore S., Balogh-Nair, Valeria, Nakanishi, Koji

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 411 KB

english, 1983

43

Optical resolution of 3-methylcycloalkanones and 5-methyl-.gamma.-butyrolactone by complexation with optically active 1,6-bis(o-halophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol

Toda, Fumio, Tanaka, Koichi, Omata, Tetsuo, Nakamura, Kazuyoshi, Oshima, Tokio

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 310 KB

english, 1983

44

Enzyme-catalyzed organic synthesis: regeneration of deuterated nicotinamide cofactors for use in large-scale enzymatic synthesis of deuterated substances

Wong, Chi Huey, Whitesides, George M.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 396 KB

english, 1983

45

Conformation and dynamics of carcinogenic N-substituted 2-aminofluorene compounds studied by NMR.

Evans, Frederick E., Miller, Dwight W.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 801 KB

english, 1983

46

Cation radical Diels-Alder reactions of electron-rich dienophiles

Pabon, Raul A., Bellville, Dennis J., Bauld, Nathan L.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 280 KB

english, 1983

47

2,6-Dimethyleneanthracenyl-4,8-dioxy. High-spin ground state of a disjoint biradical that has no Hueckel NBMO degeneracy

Seeger, David E., Berson, Jerome A.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 247 KB

english, 1983

48

Triplet excitation transfer to carotenoids from biradical intermediates in Norrish type II photoreactions of o-alkyl-substituted aromatic carbonyl compounds

Kumar, C. V., Chattopadhyay, S. K., Das, P. K.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 295 KB

english, 1983

49

Taft-Kamlet .pi.* solvatochromic polarity parameters of solid compounds

Fuchs, Richard, Stephenson, W. Kirk

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 251 KB

english, 1983

50

Conductivity measurement of x-ray absorption spectrum: rhenium LIII near-edge structure of dirhenium decacarbonyl in 2,2,4-trimethylpentane

Sham, T. K., Heald, S. M.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 290 KB

english, 1983

51

Sodium(+) ion and lithium(+) ion effects on the photoreduction of benzophenone: a picosecond absorption study

Simon, John D., Peters, Kevin S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.01 MB

english, 1983

52

Photodecomposition of alkanones in urea inclusion compounds

Casal, H. L., De Mayo, P., Miranda, J. F., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 320 KB

english, 1983

53

Azo precursors to a putative biradical in arene metal photoadditions: evidence for a novel concerted nitrogen expulsion

Sheridan, Robert S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 394 KB

english, 1983

54

An unprecedented ligand set and coordination geometry for copper(I)

Rhodes, Larry F., Huffman, John C., Caulton, Kenneth G.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 292 KB

english, 1983

55

Solid-state chemistry, kinetics, and spectroscopy of 1,2-diphenylpropylidene

Tomioka, Hideo, Hayashi, Norihiro, Izawa, Yasuji, Senthilnathan, V. P., Platz, Matthew S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 657 KB

english, 1983

56

Synthesis and structural characterization of bis[bis(dimethylphenylphosphine)dichlororhenium](n+) ion (n = 0-2): a series of complexes processing metal-metal bond orders of 4, 3.5, and 3 and the dependence of bond length upon bond order

Cotton, F. Albert, Dunbar, Kim R., Falvello, Larry R., Tomas, Milagros, Walton, Richard A.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 643 KB

english, 1983

57

Stereoelectronic control of intramolecular Michael addition reactions

Ellis, Graham W. L., Johnson, C. David, Rogers, David N.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 763 KB

english, 1983

58

Equilibrium species in cobalt(II) carbonic anhydrase

Bertini, Ivano, Lanini, G., Luchinat, C.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 365 KB

english, 1983

59

Theory of the chemical bond. 6. Accurate relationship between bond energies and electronegativity differences

Matcha, Robert L.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 455 KB

english, 1983

60

Quintet ground state of a non-Kekule tetraradical 3,6-dimethyleneanthracenyl-1,7-dioxy

Seeger, David E., Berson, Jerome A.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 394 KB

english, 1983

61

The ionic hydrogen bond. 2. Intramolecular and partial bonds. Protonation of polyethers, crown ethers, and diketones

Meot-Ner, Michael

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 712 KB

english, 1983

62

Ozonolysis of 1,1-difluoroethylene, trifluoroethylene, and perfluoroethylene: mechanism of ozonide, epoxide, and cyclopropane formation

Agopovich, John W., Gillies, Charles W.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.00 MB

english, 1983

63

Electrophilic trapping of the tautomer of 7-deoxydaunomycinone. A possible mechanism for covalent binding of daunomycin to DNA

Kleyer, Don L., Koch, Tad H.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 289 KB

english, 1983

64

Description of homoaromaticity in terms of electron distributions

Cremer, D., Kraka, E., Slee, T. S., Bader, R. F. W., Lau, C. D. H., Nguyen Dang, T. T., MacDougall, P. J.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 933 KB

english, 1983

65

Additions and Corrections - Fast Hydrolysis of Alkyl Radicals with Leaving Groups in the β Position

Koltzenburg, G., Behrens, G., Schulte-Frohlinde, D.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 69 KB

english, 1983

66

Syn and anti stereochemistry in elimination reactions producing acyclic conjugated thioesters

Mohrig, Jerry R., Schultz, Steve C., Morin, Gregg

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 299 KB

english, 1983

67

Kinetics of electron-transfer cross-reactions within redox polymers. Coatings of a protonated polylysine copolymer with incorporated electroactive anions

Anson, Fred C., Ohsaka, Takeo, Saveant, Jean Michel

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1014 KB

english, 1983

68

EPR evidence on the structure of the copper(II)-bacitracin A complex

Seebauer, Edmund G., Duliba, Edward P., Scogin, Duane A., Gennis, Robert B., Belford, R. L.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 499 KB

english, 1983

69

Interactions of the aluminum(III) ion in a model membrane system

Tracey, Alan S., Boivin, Taryn L.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 591 KB

english, 1983

70

Evidence for the necessity of double bond (13-ene) isomerization in the proton pumping of bacteriorhodopsin

Fang, Jim Min, Carriker, John D., Balogh-Nair, Valeria, Nakanishi, Koji

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 402 KB

english, 1983

71

Local conformer control in medium-ring olefin epoxidation and osmylation

Vedejs, E., Gapinski, D. M.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 430 KB

english, 1983

72

Catalysis by human leukocyte elastase: substrate structural dependence of rate-limiting protolytic catalysis and operation of the charge relay system

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 727 KB

english, 1983

73

Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry

Simon, John D., Peters, Kevin S.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 428 KB

english, 1983

74

Interruption of conjugation in polyenes bound to transition-metal fragments

Chinn, John W., Hall, Michael B.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 1.42 MB

english, 1983

75

Crystal and molecular structures of 2,11-dithia- and 1,3,10,12-tetrathia[3.3](2,6)-pyridinophanes

Newkome, George R., Pappalardo, Sebastiano, Fronczek, Frank R.

Journal:

Journal of the American Chemical Society

Year:

1983

Language:

english

File:

PDF, 277 KB

english, 1983