Volume 107; Issue 19

Main
Journal of the American Chemical Society
Volume 107; Issue 19

Journal of the American Chemical Society

Volume 107; Issue 19

1

Regioselective oxidation of phenols catalyzed by polyphenol oxidase in chloroform

Kazandjian, Rafi Z., Klibanov, Alexander M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 434 KB

english, 1985

2

Stereomutation in the Seyferth reaction

Lambert, Joseph B., Larson, Eric G., Bosch, Richard J., TeVrucht, Mollie L. E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 674 KB

english, 1985

3

Thermal behavior of C8H8 hydrocarbons. 2. Semibullvalene: kinetic and thermodynamic stability

Martin, H. D., Urbanek, T., Walsh, R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 394 KB

english, 1985

4

Formation of acrylic acid derivatives from the reaction of carbon dioxide with ethylene complexes of molybdenum and tungsten

Alvarez, Rafael, Carmona, Ernesto, Cole-Hamilton, David J., Galindo, Agustin, Gutierrez-Puebla, Enrique, Monge, Angeles, Poveda, Manuel L., Ruiz, Caridad

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 420 KB

english, 1985

5

Oxidation of phosphazine by singlet oxygen. High-field phosphorus-31 NMR spectroscopic studies of 3-phospha-1,2-dioxa-4,5-diazine and phospha-1,2-dioxetane

Akasaka, Takeshi, Sato, Rikiya, Ando, Wataru

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 265 KB

english, 1985

6

Experimental and theoretical studies of the gas-phase protonation of aliphatic phosphine oxides and phosphoramides

Bollinger, J. C., Houriet, R., Kern, C. W., Perret, D., Weber, J., Yvernault, T.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 876 KB

english, 1985

7

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.03 MB

english, 1985

8

Sequence-specific recognition of B DNA by bis(EDTA-distamycin)fumaramide

Youngquist, R. Scott, Dervan, Peter B.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 675 KB

english, 1985

9

Actinobolin via the anomeric effect

Rahman, M. Abdur, Fraser-Reid, Bert

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 356 KB

english, 1985

10

Stereospecific synthesis of rhynchosporosides, a family of fungal metabolites causing scald disease in barley and other grasses

Nicolaou, K. C., Randall, J. L., Furst, G. T.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 379 KB

english, 1985

11

The anionic oxy-claisen rearrangement of enolates of .alpha.-allyloxy ketones. A remarkable rate accelerating effect exhibited by the nature of the counterion

Koreeda, Masato, Luengo, Juan I.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 277 KB

english, 1985

12

High-quantum-yield long-lived charge separation in a photosynthetic reaction center model

Wasielewski, Michael R., Niemczyk, Mark P., Svec, Walter A., Pewitt, E. Bradley

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 276 KB

english, 1985

13

Synthesis and deuteration of (.eta.-thiophene)Ru(.eta.-C5H5)+: a model for adsorption and deuterium exchange of thiophene on hydrodesulfurization catalysts

Spies, George H., Angelici, Robert J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 299 KB

english, 1985

14

Photophysics of ruthenium complexes bound to double helical DNA

Kumar, Challa V., Barton, Jacqueline K., Turro, Nicholas J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 741 KB

english, 1985

15

Hemiacetal formation with a phenol nucleophile: simple proton transfers as rate-limiting steps

McClelland, Robert A., Devine, David B., Soerensen, Poul E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 609 KB

english, 1985

16

Chemistry and structure of the first 10-Sb-3 species

Stewart, Constantine A., Harlow, Richard L., Arduengo, Anthony J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 903 KB

english, 1985

17

Study of aromatic functional group conformations in solution by nuclear Overhauser enhancement and relaxation techniques: detection of .pi.-electron density and correlation with chemical reactivity

Kruse, Lawrence I., DeBrosse, Charles W., Kruse, Carolyn H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.07 MB

english, 1985

18

Kinetics of iron(III) porphyrin catalyzed epoxidations

Traylor, Teddy G., Marsters, James C., Nakano, Taku, Dunlap, Beth E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 406 KB

english, 1985

19

Complexation of tert-butylammonium perchlorate by crown ethers in polar solvents studied by proton NMR spectroscopy

De Boer, J. A. A., Reinhoudt, D. N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 608 KB

english, 1985

20

m-Quinodimethane, parent hydrocarbon of the m-quinonoid non-Kekule series. Low-temperature isolation and solution-phase chemical reactivity

Goodman, Joshua L., Berson, Jerome A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 2.11 MB

english, 1985

21

Nucleophilic addition of silyl enol ethers to aromatic nitro compounds: scope and mechanism of reaction

RajanBabu, T. V., Reddy, G. S., Fukunaga, Tadamichi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.48 MB

english, 1985

22

Diagonal peak suppression in 2D-NOE spectra

Harbison, Gerard S., Feigon, Juli, Ruben, David J., Herzfeld, Judith, Griffin, Robert G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.08 MB

english, 1985

23

Stereospecific total synthesis of (.+-.)-gephyrotoxin 223AB

Iida, Hideo, Watanabe, Yohya, Kibayashi, Chihiro

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 233 KB

english, 1985

24

Kinetic isotope effect study of the borderline solvolysis of isopropyl .beta.-naphthalenesulfonate

Yamataka, Hiroshi, Tamura, Shinichi, Hanafusa, Terukiyo, Ando, Takashi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 734 KB

english, 1985

25

Stereospecific formation of enolates from reaction of unsymmetrical ketenes and organolithium reagents

Baigrie, Lynn M., Seiklay, Hani R., Tidwell, Thomas T.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 858 KB

english, 1985

26

A-(modified B6)-B-[.omega.-amino(ethylamino)]-.beta.-cyclodextrin as an artificial B6 enzyme for chiral aminotransfer reaction

Tabushi, Iwao, Kuroda, Yasuhisa, Yamada, Masahiko, Higashimura, Hideyuki, Breslow, Ronald

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 271 KB

english, 1985

27

Masthead

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 146 KB

english, 1985

28

Resistivity mechanisms in phthalocyanine-based linear-chain and polymeric conductors: variation of bandwidth with geometry

Pietro, William J., Marks, Tobin J., Ratner, Mark A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 613 KB

english, 1985

29

Kinetic study of the photochlorination of 2,3-dimethylbutane and other alkanes in solution in the presence of benzene. First measurements of the absolute rate constants for hydrogen abstraction by the "free" chlorine atom and the chlorine atom-benzene .pi.-complex. Identification of these two species as the only hydrogen abstractors in these systems

Bunce, Nigel J., Ingold, Keith U., Landers, James P., Lusztyk, J., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.21 MB

english, 1985

30

Electrochemical characterization of the iron-molybdenum cofactor from Azotobacter vinelandii nitrogenase

Schultz, Franklin A., Gheller, Stephen F., Burgess, Barbara K., Lough, Samuel, Newton, William E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 697 KB

english, 1985

31

Anion affinities of transition-metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions

Lane, Kelley R., Sallans, Larry, Squires, Robert R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 923 KB

english, 1985

32

Two molecular hydrogen complexes: trans-[M(.eta.2-H2)(H)(PPh2CH2CH2PPh2)2]BF4 (M = Fe, Ru). The crystal structure determination of the iron complex

Morris, Robert H., Sawyer, Jeffery F., Shiralian, Mahmoud, Zubkowski, Jeffrey

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 284 KB

english, 1985

33

Ab initio mechanisms for the addition of methyllithium, lithium hydride, and their dimers to formaldehyde

Kaufmann, Elmar, Schleyer, Paul v. R., Houk, Kendall N., Wu, Yun Dong

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 370 KB

english, 1985

34

Alkyl migration in an iron(II) alkylidene: a new route to a stabilized bridgehead olefin

Bly, Robert S., Hossain, M. Mahmun, Lebioda, Lukasz

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 289 KB

english, 1985

35

Possible biomimetic synthesis of .beta.-lactams

Kaneko, Takushi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 406 KB

english, 1985

36

Phase transitions affecting intramolecular electron transfer in mixed-valence trinuclear iron acetate complexes

Oh, Seung M., Kambara, Takeshi, Hendrickson, David N., Sorai, Michio, Kaji, Kazutoshi, Woehler, Scott E., Wittebort, Richard J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 263 KB

english, 1985

37

Gas-phase reactions of free vinyl cation with benzene and free phenylium ion with ethylene. A comparative FT-ICR and nuclear decay study

Fornarini, Simonetta, Speranza, Maurizio

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 788 KB

english, 1985

38

Dimerization of the [8]annulene anion radical

Stevenson, Gerald R., Nebgen, Mark A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 489 KB

english, 1985

39

End-to-end cyclization of hydrocarbon chains: temperature effects on an intramolecular phosphorescence quenching reaction in solution

Mar, Andrew, Winnik, Mitchell A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 870 KB

english, 1985

40

Insertion of elemental sulfur into tungsten-carbon bonds

Legzdins, Peter, Sanchez, Luis

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 235 KB

english, 1985

41

Photocyclization of o-tert-butylbenzophenone

Wagner, Peter J., Giri, B. P., Scaiano, J. C., Ward, D. L., Gabe, E., Lee, F. L.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.06 MB

english, 1985

42

Adsorption and decomposition of formaldehyde on the ruthenium(001) surface: the spectroscopic identification of .eta.2-formaldehyde and .eta.2-formyl

Anton, A. B., Parmeter, J. E., Weinberg, W. H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 371 KB

english, 1985

43

Internal molecular motion as forerunner of a phase change involving conformational isomerization

Yang, Qing Chuan, Richardson, Mary Frances, Dunitz, Jack D.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 364 KB

english, 1985

44

Common intermediates in the flash photolysis of Vaska's compound IrCl(CO)(PPh3)2 and its dihydride adduct H2IrCl(CO)(PPh3)2. Implications with regard to reductive elimination mechanisms

Wink, David A., Ford, Peter C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 300 KB

english, 1985

45

A stereochemical imperative in dehydrogenases: new data and criteria for evaluating function-based theories in bioorganic chemistry

Benner, Steven A., Nambiar, Krishnan P., Chambers, Geoffrey K.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 808 KB

english, 1985

46

Stereoselective synthesis of .gamma.,.delta.-epoxy-.beta.-methyl-.gamma.-(trimethylsilyl)alkanols. Synthesis of the C(1)-C(7) segment of 6-deoxyerythronolide B

Kobayashi, Yuichi, Uchiyama, Hiroshi, Kanbara, Hiroshi, Sato, Fumie

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 409 KB

english, 1985

47

Efficient triple coupling reaction to produce a self-adjusting molecular cage

O'Krongly, David, Denmeade, Samuel R., Chiang, Michael Y., Breslow, Ronald

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 915 KB

english, 1985

48

Total synthesis of (.+-.)-antheridium-inducing factor (AAn) of the Fern Anemia phyllitidis. Clarification of stereochemistry

Corey, E. J., Myers, Andrew G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 447 KB

english, 1985

49

Total synthesis of (-)-upial

Taschner, Michael J., Shahripour, Abdulsadeh

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 362 KB

english, 1985

50

Protons on a cluster surface. Reversible generation of agostic (carbon-hydrogen-metal) hydrogens from iron hydrides (iron-hydrogen-iron) on a saturated triiron cluster

Vites, J. C., Jacobsen, G., Dutta, T. K., Fehlner, T. P.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 424 KB

english, 1985

51

Ultrasound-induced electrochemical synthesis of the anions selenide (Se22-, Se2-), and telluride (Te22-, and Te2-)

Gautheron, Bernard, Tainturier, Gerard, Degrand, Chantal

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 402 KB

english, 1985

52

Metabolites of the marine prosobranch mollusk Lamellaria sp

Andersen, Raymond J., Faulkner, D. John, He, Cun Heng, Van Duyne, Gregory D., Clardy, Jon

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 546 KB

english, 1985

53

Synthesis and thermal rearrangement of homopentafulvalenes

Hafner, Klaus, Thiele, Georg F.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 750 KB

english, 1985

54

Energetics and hydration structures of a solvated gramicidin A transmembrane channel for potassium and sodium cations

Kim, Kwang S., Clementi, E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 2.33 MB

english, 1985

55

The tungsten(IV) aqua ion

Segawa, Masashi, Sasaki, Yoichi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 305 KB

english, 1985

56

A synthesis of methoxatin

Buchi, George, Botkin, James H., Lee, Gary C. M., Yakushijin, Kenichi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 260 KB

english, 1985

57

Stable simple enols. 10. 500-MHz proton NMR of trimesitylethenol and deuterated analogs: complete signal assignments and direct determination of equilibrium steric isotope effects from the NMR integrals of the isotopomeric enols

Biali, Silvio E., Rappoport, Zvi, Hull, William E.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.28 MB

english, 1985

58

Stereochemistry and mechanism of m-cyclophane formation in the 1,4-additions of dienes to the m-quinodimethane biradical. On the question of formal 1,2-addition via sequential 1,4-addition and rearrangement

Goodman, Joshua L., Berson, Jerome A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 553 KB

english, 1985

59

Formation of carbon dioxide and a four-membered 1,3-dimetallacycle by deoxygenation of a ketone with [Rh(CO)2Cl]2

Suggs, J. William, Wovkulich, Michael J., Lee, Ken S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 405 KB

english, 1985

60

A systematic approach to calculate molecular properties of organosulfur compounds containing the carbon-sulfur (Csp2-S) bond

Kao, James, Eyermann, Charles, Southwick, Everett, Leister, Diane

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.19 MB

english, 1985

61

Structures of three lithium ester enolates by x-ray diffraction: derivation of reaction path for cleavage into ketene and alcoholate

Seebach, Dieter, Amstutz, Rene, Laube, Thomas, Schweizer, W. Bernd, Dunitz, J. D.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 712 KB

english, 1985

62

Direct observation of the aziridinium imide intermediates in the reaction of biadamantylidene with triazolinediones

Nelsen, Stephen F., Kapp, Daniel L.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 267 KB

english, 1985

63

The tetrasilabicyclo[1.1.0]butane system: preparation and characterization of 1,3-di-tert-butyl-2,2,4,4-tetrakis(2,6-diethylphenyl)tetrasilabicyclo[1.1.0]butane

Masamune, Satoru, Kabe, Yoshio, Collins, Scott, Williams, David J., Jones, Ray

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 288 KB

english, 1985

64

Mercuration of the selenium-selenium bond of a chelating diselenium group with mercury (Hg0): preparation and crystal structure of [(dmpe)2Ir(.mu.-Se)2Hg]4Cl4

Ginsberg, A. P., Sprinkle, C. R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 439 KB

english, 1985

65

Kinetics of polyatomic free radicals produced by laser photolysis. 5. Study of the equilibrium methyl + oxygen .dblarw. CH3O2 between 421 and 538.degree.

Slagle, Irene R., Gutman, David

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.32 MB

english, 1985

66

General method for generation of 3-siloxyallylmetallic species and their synthetic application

Enda, Jun, Kuwajima, Isao

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 950 KB

english, 1985

67

A proton NMR study of reduced paramagnetic tris(2,2'-bipyridine) complexes of iron(II), ruthenium(II) and osmium(II)

Ohsawa, Yasuhiko, DeArmond, M. Keith, Hanck, Kenneth W., Moreland, Charles G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 520 KB

english, 1985

68

Fluxional behavior in the solid state: bullvalene

Meier, B. H., Earl, William L.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 398 KB

english, 1985

69

Ab initio studies of the C3H4 surface I. SCF and CI study of structures and stabilities of isomers

Honjou, N., Pacansky, J., Yoshimine, M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.02 MB

english, 1985

70

Chemistry of exciplexes. 19. Exciplex-promoted electron transfer in 1-(phenylamino)-3-(9-anthryl)propanes

Yang, Nien Chu C., Gerald, Rex, Wasielewski, Michael R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 282 KB

english, 1985

71

Hydrogen/deuterium exchange and addition in the reaction of (.eta.4-C4H6)Fe(CO)-.cntdot. with deuterium(D2). An anionic model for homogeneous hydrogenation

McDonald, Richard N., Schell, Philip L., Chowdhury, A. Kasem

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 270 KB

english, 1985

72

Regio- and diastereoselective preparation of aldols from .alpha.-branched ketone enolates generated from BHT ester enolates and organolithium reagents. In situ generation and trapping of ketenes from ester enolates

Haener, Robert, Laube, Thomas, Seebach, Dieter

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.08 MB

english, 1985

73

Dynamic cis-trans isomerization of retinal in dark-adapted bacteriorhodopsin

Seltzer, Stanley, Zuckermann, Ron

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 379 KB

english, 1985