Volume 107; Issue 4

Main
Journal of the American Chemical Society
Volume 107; Issue 4

Journal of the American Chemical Society

Volume 107; Issue 4

1

Fluoride and chloride affinities of main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of Lewis acidities from ion cyclotron resonance halide-exchange equilibria

Larson, J. W., McMahon, T. B.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.04 MB

english, 1985

2

Electronegativity equalization: application and parametrization

Mortier, Wilfried J., Van Genechten, Karin, Gasteiger, Johann

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 847 KB

english, 1985

3

Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes

Miyaura, Norio, Yamada, Kinji, Suginome, Hiroshi, Suzuki, Akira

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.01 MB

english, 1985

4

Photoresponsive molecular tweezers. Photoregulated ion capture and release using thioindigo derivatives having ethylenedioxy side groups

Irie, Masahiro, Kato, Masatoshi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.30 MB

english, 1985

5

Biosynthesis of clavulanic acid: origin of the C3 unit

Townsend, Craig A., Ho, Meng Fei

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 378 KB

english, 1985

6

Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis

Berg, Jeremy M., Holm, R. H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1008 KB

english, 1985

7

Reductive transformations. 5. Alternative routes for reductive alkylations in liquid ammonia and their selection via spectroscopic evidence

Muellen, Klaus, Huber, Walter, Neumann, Gerd, Schnieders, Christoph, Unterberg, Heinz

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 892 KB

english, 1985

8

Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties

Berg, Jeremy M., Holm, R. H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.13 MB

english, 1985

9

Carbocation behavior in norbornyl-fused norbornyl systems. The kinetic and chemical consequences of fusing two norbornane units across framework bonds of various type

Paquette, Leo A., DeLucca, George, Ohkata, Katsuo, Gallucci, Judith C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.16 MB

english, 1985

10

Two-alkyne annulations of transition-metal carbene complexes via in situ generated vinyl carbene complexes

Wulff, William D., Kaesler, Ralph W., Peterson, Glen A., Tang, Peng Cho

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 332 KB

english, 1985

11

1,8-biphenylenediol is a double-hydrogen-bonding catalyst for reaction of an epoxide with a nucleophile

Hine, Jack, Linden, Shwn Meei, Kanagasabapathy, V. M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 274 KB

english, 1985

12

Detailed rate studies on the Wittig reaction of nonstabilized phosphorus ylides via phosphorus-31, proton, carbon-13 NMR spectroscopy. Insight into kinetic vs. thermodynamic control of stereochemistry

Maryanoff, Bruce E., Reitz, Allen B., Mutter, Martin S., Inners, Ruth R., Almond, Harold R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 438 KB

english, 1985

13

The potential dependence of electrical conductivity and chemical charge storage of poly(pyrrole) films on electrodes

Feldman, B. J., Burgmayer, Paul, Murray, Royce W.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 947 KB

english, 1985

14

NMR chemical shift and NMR isotope shift evidence for the influence of nonbonded interactions on charge distribution in .alpha.,.beta.-unsaturated methoxycarbenium ions

Forsyth, David A., Osterman, Virginia M., DeMember, John R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 605 KB

english, 1985

15

Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2

Evans, William J., Grate, Jay W., Choi, Henry W., Bloom, Ira, Hunter, William E., Atwood, Jerry L.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 825 KB

english, 1985

16

Synthesis and characterization of blocked and ligand-appended hemes derived from atropisomeric meso-diphenylporphyrins

Young, Richard, Chang, Chris K.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.48 MB

english, 1985

17

Theoretical study of the ground and excited singlet states of styrene

Hemley, R. J., Dinur, U., Vaida, V., Karplus, Martin

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.20 MB

english, 1985

18

Species specificity of long-range electron transfer within the complex between zinc-substituted cytochrome c peroxidase and cytochrome c

Ho, Pui Shing, Sutoris, Carol, Liang, Nong, Margoliash, E., Hoffman, Brian M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 327 KB

english, 1985

19

Hydrolysis chemistry of the metallocene dichlorides M(.eta.5-C5H5)2Cl2, M = titanium, vanadium, or zirconium. Aqueous kinetics, equilibria, and mechanistic implications for a new class of antitumor agents

Toney, Jeffrey H., Marks, Tobin J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 969 KB

english, 1985

20

Molecular free surface: a novel method of calculation and its uses in conformational studies and in organic crystal chemistry

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 660 KB

english, 1985

21

Divalent metal ion catalysis in the hydrolysis of esters of picolinic acid. Metal ion promoted hydroxide ion and water catalyzed reactions

Fife, Thomas H., Przystas, Theodore J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 830 KB

english, 1985

22

Dependence of rate constants for photoinduced charge separation and dark charge recombination on the free energy of reaction in restricted-distance porphyrin-quinone molecules

Wasielewski, Michael R., Niemczyk, Mark P., Svec, Walter A., Pewitt, E. Bradley

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 393 KB

english, 1985

23

Book Reviews

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 296 KB

english, 1985

24

Models for the interaction of zinc(2+) ion with DNA. The synthesis and x-ray structural characterization of two octahedral zinc complexes with monomethyl phosphate esters of 6-oxopurine 5'-monophosphate nucleotides

Miller, Sandra K., VanDerveer, Donald G., Marzilli, Luigi G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.00 MB

english, 1985

25

Evidence for two different radical cation types derived from methylenecyclopropane

Miyashi, Tsutomu, Takahashi, Yasutake, Mukai, Toshio, Roth, Heinz D., Schilling, Marcia L. M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 289 KB

english, 1985

26

An unusual CIDEP observation in the photochemical reactions of benzophenone and ascorbyl palmitate: the elusive neutral ascorbate radical

Craw, Marjory T., Depew, M. Catherine, Wan, Jeffrey K. S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 258 KB

english, 1985

27

Recognition of NMR proton spin systems of cyclosporin A via heteronuclear proton-carbon long-range couplings

Kessler, Horst, Bermel, Wolfgang, Griesinger, Christian

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 271 KB

english, 1985

28

Electron spin-echo modulation studies of doxylstearic acid spin probes in sodium and tetramethylammonium dodecyl sulfate micelles: interaction of the spin probe with deuterated water and with deuterated terminal methyl groups in the surfactant molecules

Szajdzinska-Pietek, E., Maldonado, Rene, Kevan, Larry, Jones, Richard R. M., Coleman, Michael J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 632 KB

english, 1985

29

Photoreactivities of o-alkoxy- and o-tert-butylphenyl ketones: a dramatic example of conformational inversion of selectivity

Wagner, Peter J., Meador, Michael A., Giri, B. P., Scaiano, J. C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 274 KB

english, 1985

30

Biosynthesis of clavulanic acid: origin of the C5 unit

Townsend, Craig A., Ho, Meng Fei

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 296 KB

english, 1985

31

Electrophilic cleavage of cyclopropanes. Acetolysis of bicyclic and tricyclic cyclopropanes

Wiberg, Kenneth B., Kass, Steven R., De Meijere, Armin, Bishop, K. C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 556 KB

english, 1985

32

Allenyldiene electrocyclization, a stereospecific tandem center-axis-center chirality transfer: synthesis of drimatrienes and related trans-decalins

Okamura, William H., Peter, Roland, Reischl, Wolfgang

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.10 MB

english, 1985

33

Charge density topological approach to the dinorcaradiene .dblharw. [10]annulene equilibrium in some 11,11-disubstituted 1,6-methano[10]annulenes

Gatti, Carlo, Barzaghi, Mario, Simonetta, Massimo

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.34 MB

english, 1985

34

Electrophilic cleavage of cyclopropanes. Acetolysis of bicyclo[2.1.0]pentane and bicyclo[3.1.0]hexane

Wiberg, Kenneth B., Kass, Steven R., Bishop, K. C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 821 KB

english, 1985

35

Synthesis, structural characterization, and stereospecificity in the formation of bimetallic rhodacarborane clusters containing rhodium-hydrogen-boron bridge interactions

Behnken, Paul E., Marder, Todd B., Baker, R. Thomas, Knobler, Carolyn B., Thompson, Michael R., Hawthorne, M. Frederick

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.03 MB

english, 1985

36

Anion effects on the kinetics of sodium(1+) ion-18-crown-6 complexation in tetrahydrofuran solutions

Strasser, Bruce O., Hallenga, Klaas, Popov, Alexander I.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 474 KB

english, 1985

37

Calculation of substrate dissociation constants from steady-state isotope effects in enzyme-catalyzed reactions

Klinman, Judith P., Matthews, Rowena G.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 384 KB

english, 1985

38

Structures of organic cations in the gas phase. Neutral products from fluoride abstraction examined by NMR

Redman, Eric W., Johri, Kamalesh K., Morton, Thomas Hellman

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 673 KB

english, 1985

39

Dependence of carbon-carbon and carbon-hydrogen bond activation on d band position: acetylene on platinum(111) and iron(100). An electrochemical model

Mehandru, S. P., Anderson, Alfred B.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 777 KB

english, 1985

40

Stable simple enols. 8. Synthesis and keto .dblharw. enol equilibria of the elusive 2,2-dimesitylethanal and 1,2,2-trimesitylethanone. Conformations of 1,2,2-trimesitylethanone and 1,2,2-trimesitylethanol

Biali, Silvio E., Rappoport, Zvi

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.16 MB

english, 1985

41

Unique structural features of a hexarhodium-.mu.4-tert-butylarsinidene complex, formed via arsenic-carbon bond cleavage. Synthesis and structure of a hexarhodium pentagonal pyramid: Rh6(CO)9(.mu.-CO)2(.mu.-tert-Bu2As)2(.mu.4-tert-BuAs)

Jones, Richard A., Whittlesey, Bruce R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 291 KB

english, 1985

42

Masthead

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 140 KB

english, 1985

43

The synthesis and structure of the first 10-As-3 species

Culley, Scott Anthony, Arduengo, Anthony J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 792 KB

english, 1985

44

Electrochemical reduction and reoxidation accompanied by reversible geometric isomerization. Electrochemistry of bis(dicarbonyl-.mu.-di-tert-butylphosphidorhodium). Isolation and x-ray crystal structure of bis(tetra-n-butylammonium) bis(dicarbonyl-.mu.-di-tert-butylphosphidorhodate)

Gaudiello, John G., Wright, Thomas C., Jones, Richard A., Bard, Allen J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 938 KB

english, 1985

45

Photochemical rearrangements of o- and m-dichlorobenzene cations to p-dichlorobenzene cation in solid argon

Friedman, Ronald S., Andrews, Lester

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 631 KB

english, 1985

46

Intermolecular conversion over a low barrier. 3. Gas-phase NMR studies of a hydrogen-bond association

Bauer, S. H., Yamazaki, Tomoko, Lazaar, K. I., Chiu, N. S.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 432 KB

english, 1985

47

Electrophilic cleavage of cyclopropanes. Acetolysis of alkylcyclopropanes

Wiberg, Kenneth B., Kass, Steven R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 916 KB

english, 1985

48

Copper carbonyls, Cu(CO) and Cu(CO)3: matrix isolation ESR study

Kasai, Paul H., Jones, Paul M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 592 KB

english, 1985

49

Picosecond photodissociation of six-coordinate iron(II) porphyrins

Dixon, Dabney White, Kirmaier, Christine, Holten, Dewey

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 853 KB

english, 1985

50

On a tandem 1,2-elimination/[1,7]-sigmatropic shift: synthesis of double bond shifted isomers of vitamin A

Chauhan, Yeshpal S., Chandraratna, Roshantha A. S., Miller, Donald A., Kondrat, Richard W., Reischl, Wolfgang, Okamura, William H.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 862 KB

english, 1985

51

Meso deuterium NMR hyperfine shift as a probe for determining five- or six-coordination at heme iron binding site in ferric high-spin hemoproteins

Morishima, Isao, Shiro, Yoshitsugu, Wakino, Tomoyuki

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 450 KB

english, 1985

52

Comparative study of nucleophilic addition to free and metal-coordinated carbocations

Alavosus, T. J., Sweigart, D. A.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 381 KB

english, 1985

53

Donor stereospecificity of palladium-mediated cycloadditions. A case of distal attack of acceptor on donor

Trost, Barry M., Nanninga, Thomas N.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 257 KB

english, 1985

54

Aromatic stability of heterocyclic conjugated systems

Randic, M., Trinajstic, N., Knop, J. V., Jericevic, Z.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.24 MB

english, 1985

55

MNDO and ab initio study of the mechanism of organolithium amination by lithium alkoxyamides

McKee, Michael L.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 633 KB

english, 1985

56

Mechanistic and exploratory organic photochemical series. 142. Dynamic isotopic dilution as a general method for ascertaining partition of photochemical pathways potentially utilizing nondiscernible intermediates: application to a new reaction

Zimmerman, Howard E., Carpenter, Clint W., Weber, Andrew M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 388 KB

english, 1985

57

Trimethylenemethane dianion and the controversial notion of Y-aromaticity

Agranat, Israel, Skancke, Anne

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 689 KB

english, 1985

58

Decomposition of phosphonate esters adsorbed on aluminum oxide

Templeton, M. K., Weinberg, W. Henry

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 791 KB

english, 1985

59

Conformational analysis by ESR spectroscopy. 3. Radicals derived from cyclohexanone

Walter, H. F., Beaudry, W. T., Camaioni, D. M., Pratt, D. W.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.05 MB

english, 1985

60

Kinetically stable conformers of 3,4,5,6-tetramethyl-9,10-dihydroxy-9,10-dihydrophenanthrene as probes of the conformer specificity of UDPglucuronosyltransferase

Armstrong, Richard N., Lewis, Deborah A., Ammon, Herman L., Prasad, Satya M.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 264 KB

english, 1985

61

Hexacyclen complexes of inorganic anions. 2. Bonding forces, structures, and selectivity

Gelb, Robert I., Lee, Brenda T., Zompa, Leverett J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.07 MB

english, 1985

62

Ab initio second-order Moeller-Plesset calculation of the vibrational spectrum of tetrahedrane

Hess, B. Andes, Schaad, L. J.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 192 KB

english, 1985

63

Aggregation of a bacteriochlorophyllide d: direct evidence for a nonsymmetric aggregate in solution

Abraham, Raymond J., Smith, Kevin M., Goff, Dane A., Bobe, Frank W.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 311 KB

english, 1985

64

Valence transitions in cis- and trans-hexatrienes

McDiarmid, Ruth, Sabljic, A., Doering, J. P.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 495 KB

english, 1985

65

Photochemical disproportionation of bis(.eta.5-methylcyclopentadienyl)dimolybdenum hexacarbonyl by halides

Stiegman, Albert E., Tyler, David R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 533 KB

english, 1985

66

Synthesis and crystal structure of the bismuth-iron carbonyl cluster [Et4N]2[Bi4Fe4(CO)13]. Discovery of a hybrid Zintl-metal carbonyl cluster

Whitmire, Kenton H., Churchill, Melvyn Rowen, Fettinger, James C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 242 KB

english, 1985

67

Trifluoroethylidynesulfur trifluoride, CF3C.tplbond.SF3, and its dimer

Poetter, Brigitte, Seppelt, Konrad, Simon, Arndt, Peters, Eva Maria, Hettich, Bernhard

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 749 KB

english, 1985

68

Coupling of acyl and iminoacyl groups on zirconium and .sigma.2,.pi.-coordination of the resulting enamidolate ligand

McMullen, Anne K., Rothwell, Ian P., Huffman, John C.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 262 KB

english, 1985

69

Competing pathways in the photolysis of bicyclo[1.1.0]butane

Becknell, Alan F., Berson, Jerome A., Srinivasan, R.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 401 KB

english, 1985

70

A tungsten-bismuth cluster featuring dibismuth as a four-electron donor and a bridging bismuthinidene

Arif, Atta M., Cowley, Alan H., Norman, Nicholas C., Pakulski, Marek

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 276 KB

english, 1985

71

Charge-transfer complexes of aryl derivatives of Group 14 and 15 elements with tetracyanoethylene

Frey, John E., Cole, Roger D., Kitchen, Elizabeth C., Suprenant, Lori M., Sylwestrzak, Mary Sue

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 947 KB

english, 1985

72

Metastable iron/sulfur clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3- clusters (L = Cl-, Br, I-, RS-, RO-) and the structure of [(C2H5)4N]3[Fe6S6Cl6]

Kanatzidis, M. G., Hagen, W. R., Dunham, W. R., Lester, R. K., Coucouvanis, Dimitri K.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 1.57 MB

english, 1985

73

Mechanistic information from infrared multiple photon decomposition. The ethylisopropylamine proton-transfer system

Moylan, Christopher R., Brauman, John I.

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 598 KB

english, 1985

74

Chemical reactions on clusters. 4. Gas phase unimolecular decomposition of the acetone and acetone-d6 ions in association with argon and carbon dioxide clusters

Journal:

Journal of the American Chemical Society

Year:

1985

Language:

english

File:

PDF, 872 KB

english, 1985